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Fuel cell and vehicles
Zlámal, Josef ; Kloss, Ondřej (referee) ; Kaplan, Zdeněk (advisor)
In the first part of this work a historical development of fuel cell, description of its construction and function including a comparison of currently used fuel cells is presented. The next part of this work is focused on fuel for fuel cells, its production, distribution and storage. The last chapters are dealing with fuel cell automobile, project of particular car companies and author´s assessment of individual fuel cell systems.
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Fuell cells
Sedláček, Tomáš ; Elcner, Jakub (referee) ; Hejčík, Jiří (advisor)
This bachelor thesis describes the distribution of fuel cells, principle of their operation and composition of the individual cell types. It states the advantages or disadvantages of the individual cell types and summarizes their basic parameters. This thesis also refers to the current state of development of fuel cells and convenient areas of their application.
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Fuel cells in personal transport
Říha, Stanislav ; Blaťák, Ondřej (referee) ; Zháňal, Lubor (advisor)
This thesis is oriented to historical evolution of fuel cell, his total analysis, description of single disadvantage and advantage with which fuel cells battle. An other reason for urgency of using alternative fuel, brief description of car market and possible guess of fuel cell's future in personal transport are involved in an other part of this thesis. The end of the thesis deal with cars of fuel cells split in parts according to single car companies.
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New Characterisation Approaches for Carbon Ionic Liquid Electrodes (CILES)
Mikysek, T. ; Stočes, M. ; Švancara, I. ; Vytřas, K. ; Ludvík, Jiří
Within this study, some new approaches to characterize the carbon paste mixtures and the respective carbon ionic liquid electrodes (CILEs) are presented and their properties discussed. Particular attention has been paid to the changes of the resistivity, relative to the dependence on composition of the CILE. Three types of carbon ionic liquid pastes were examined, and for the interpretation of experimental data, the results were compared with those of "classic" carbon paste electrode (CPE) based on graphite powder. Some problems connected with homogeneity and stability of carbon pastes are also discussed.
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Reproducibility of working electrodes in voltammetry
Josypčuk, Bohdan ; Heyrovský, Michael
In voltammetry the working electrode is the source of signal from which the due information is gained. A transition from the dropping mercury electrode to any kind of stationary electrode is inevitably accompanied by worsened reproducibility of measurements, the transition to the hanging mercury drop electrode is accompanied by a certain instrumental complication. When solving a concrete task, the precision of reproducibility of measurements often becomes the decisive factor for selecting a particular type of working electrode, or for taking voltammetry as the method of choice. This work is the beginning of a wider study which includes comparison of different working electrodes and finding of optimal conditions guaranteed reproducible measurements of various electrode processes (reduction, oxidation, accumulation, adsorption and catalysis).
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Voltammetric measurement of H.sub.2./sub.O.sub.2./sub. concentration in aqua-organic solutions
Kurc, L. ; Floriš, T. ; Josypčuk, Bohdan
In this work was tested the applicability of voltammetry and of meniscus silver solid amalgam electrode for determination H2O2 in presence of organic species (solvent, substrate or product of Baeyer-Villiger oxidation of cycloketones to lactones). Hydrogen peroxide can be measured in its wide concentration interval in different aqua-organic solutions. The slope of H.sub.2./sub.O.sub.2./sub. concentration dependence decreases with increasing 1,4-dioxane concentration. 1,4-dioxane in mixture with water can be used up to its concentration 80 vol. %. Model species, which represent reactants and products of Baeyer-Villiger oxidation, influence calibration dependence individually and their effect is not possible to estimate. Hence, quantitative hydrogen peroxide determination in probes of reactive mixture, which have different composition, should be carried out by standard addition method.
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