Název:
Application of affinity capillary electrophoresis for quantitative characterization of hexaarylbenzene-based receptor binding with alkali metal ions in methanol
Autoři:
Ehala, Sille ; Makrlík, E. ; Toman, Petr ; Kašička, Václav Typ dokumentu: Příspěvky z konference Konference/Akce: International Symposium Advances in Chromatography and Electrophoresis & Chiranal 2010, Olomouc (CZ), 2010-02-08 / 2010-02-11
Rok:
2010
Jazyk:
eng
Abstrakt: Affinity capillary electrophoresis was found to be suitable and effective tool for the quantitative evaluation of strong as well as weak interactions between hexaarylbenzene-based receptor and several alkali metal ions in methanol. The selectivity of the above receptor expressed by binding constants towards alkali metal ions was found to increase in the order of Na+ < Li+ < K+ < Cs+ < Rb+.
Klíčová slova:
binding constant; capillary affinity electrophoresis; hexaarylbenzene-based receptor Číslo projektu: CEZ:AV0Z40550506 (CEP), CEZ:AV0Z40500505 (CEP), GA203/08/1428 (CEP), GA203/09/0675 (CEP), 1ET400500402 (CEP) Poskytovatel projektu: GA ČR, GA ČR, GA AV ČR Zdrojový dokument: Proceedings of the International Symposium Advances in Chromatography and Electrophoresis & Chiranal 2010, ISBN 978-80-244-2470-5
Instituce: Ústav organické chemie a biochemie AV ČR
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Informace o dostupnosti dokumentu:
Dokument je dostupný v příslušném ústavu Akademie věd ČR. Původní záznam: http://hdl.handle.net/11104/0185626