Original title: Application of affinity capillary electrophoresis for quantitative characterization of hexaarylbenzene-based receptor binding with alkali metal ions in methanol
Authors: Ehala, Sille ; Makrlík, E. ; Toman, Petr ; Kašička, Václav
Document type: Papers
Conference/Event: International Symposium Advances in Chromatography and Electrophoresis & Chiranal 2010, Olomouc (CZ), 2010-02-08 / 2010-02-11
Year: 2010
Language: eng
Abstract: Affinity capillary electrophoresis was found to be suitable and effective tool for the quantitative evaluation of strong as well as weak interactions between hexaarylbenzene-based receptor and several alkali metal ions in methanol. The selectivity of the above receptor expressed by binding constants towards alkali metal ions was found to increase in the order of Na+ < Li+ < K+ < Cs+ < Rb+.
Keywords: binding constant; capillary affinity electrophoresis; hexaarylbenzene-based receptor
Project no.: CEZ:AV0Z40550506 (CEP), CEZ:AV0Z40500505 (CEP), GA203/08/1428 (CEP), GA203/09/0675 (CEP), 1ET400500402 (CEP)
Funding provider: GA ČR, GA ČR, GA AV ČR
Host item entry: Proceedings of the International Symposium Advances in Chromatography and Electrophoresis & Chiranal 2010, ISBN 978-80-244-2470-5

Institution: Institute of Organic Chemistry and Biochemistry AS ČR (web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences.
Original record: http://hdl.handle.net/11104/0185626

Permalink: http://www.nusl.cz/ntk/nusl-41462


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Research > Institutes ASCR > Institute of Organic Chemistry and Biochemistry
Conference materials > Papers