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Simultaneous online determination of nitric acid and nitrates in ambient air
Alexa, Lukáš ; Čmelíková, D. ; Cigánková, Hana ; Mikuška, Pavel
The innovated method for the simultaneous online determination of HNO3/NO3- in ambient air was developed. Due to high sensitivity of CLD (LOD = 5.1 nM in water solution, 3 s/n) no preconcentration method is required. The online methods were compared with the results obtained with the offline method based on sampling using filters and dry denuders (DD) covered by 0.5% NaF with subsequent analysis by ion chromatography (model ICS-2100, Dionex, USA) and capillary electrophoresis (model Agilent 7100, Agilent Technologies, USA).
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Forest springs, a safe source of drinking water?
Mikuška, Pavel ; Alexa, Lukáš ; Kouřilová, S. ; Cigánková, Hana ; Křůmal, Kamil ; Itterheimová, Petra ; Kubáň, Petr ; Matoušek, Tomáš ; Barešová, Magdalena ; Pivokonský, Martin
Water from 25 forest springs was characterized for basic physical parameters and chemical and bacteriological composition. Chemical composition was mostly within limits for drinking water, but bacteriological results indicate faecal pollution of water in majority studied springs.
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Where and how much water do trees transport? Modelling the impact of spruce and beech stands on soil water fluxes during extreme climatic conditions
Zelíková, Nikol ; Šípek, Václav
Soil moisture links processes that influence the entire hydrological cycle and thus the availability of water resources. One important factor influencing these processes is the presence of vegetation. Research on the interactions between vegetation, its management and the processes affecting soil water fluxes is of particular importance in times of ongoing climate change and land cover changes. However, the complexity of these interactions, further influenced by differences between plant species, makes this research more difficult. Land cover change is also taking place in Czechia, specifically in the replacement of spruce monocultures by beech. Therefore, this study investigates the influence of two types of forest stands, spruce (Picea abies) and beech (Fagus sylvatica), on the soil water regime in the experimental Liz catchment in Bohemian Forest, Czechia. This was performed by (1) evaluating differences in soil moisture based on twenty years of measured data and (2) obtaining the two components of the soil water balance (transpiration and percolation) at two plots (beech and spruce) using a soil water balance model. Analysis of the long-term soil moisture data show slightly lower soil moisture values under the beech stands, which disappear when comparing the annual mean values. Differences are evident when evaluating average soil moisture data with depth, where the topmost layer of the soil profile at the spruce site has on average 6% higher soil water content than beech. At the start of the growing season the soil moisture was initially drier under spruce, due to its earlier start of transpiration. This difference was reduced over the season by the intensive transpiration of beech. The outputs of the balance model indicated a higher rate of actual evapotranspiration of beech and a higher rate of percolation of spruce every year. This effect was more pronounced over the dry years, whereas in years with sufficient rainfall the differences were minimal. Thus, the replacement of spruce trees by beech trees may affect the rate of groundwater recharge.
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Time variabilty of soil hydraulic properties and their impact on soil moisture estimation
Šípek, Václav ; Vlček, Lukáš ; Tesař, Miroslav ; Zelíková, Nikol ; Hnilica, Jan
The study was focused on the temporal variability of saturated hydraulic conductivity in an experimental plot covered by spruce forest and investigated benefits of its incorporation into soil water balance model. The results showed that the higher saturated hydraulic conductivity (33.6-44.8 cm hr-1) was observed in summer period compared to lower values (13.2-22.3 cm hr-1) in the winter period. The use of seasonally variabile saturated hydraulic conductivity improved the efficiency of soil water balance model in terms of lower root mean square error between observed and simulated volumetric soil water content by 33.2 %. The Nash-Sutcliffe coefficient rose from 0.34 to 0.68.
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Hydrology of small basins 2023
Hnilicová, Soňa ; Tesař, Miroslav
The book is a collection of scientific contributions to the Conference "Hydrology of small basins". The conference topics were: 1. Changes in the regime of water resources in small basins; 2. Complex monitoring a and water storage balance in small basins; 3. Hydrological extremes (flash floods, drought); 4. Effect of land use and land cover on water balance; 5. Hydrophobicity and transportation processes in soil; 6. Hydrological modelling und uncertainties; 7. Biogeochemical fluxes in a small watershed and eutrophication of surface waters; 8. Mountainous experimental small basins (deposited precipitation, snow regime, …); 9. New methods, techniques and instrumentation in hydrology and hydroecology.\n
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Speciation analysis employing hydride generation
Matoušek, Tomáš
The lecture presented employing of different ways of hydride generation- selective generation, postcolumn generation and cryotrapping- useful of element speciation analysis. Examples from our laboratory covered applications from the field of clinical, food and natural water analysis.
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