Název:
A Short Overview of the Electrochemistry of Helical Polyaromatics.
Autoři:
Vacek, J. ; Hrbáč, J. ; Zatlouklová, M. ; Storch, Jan Typ dokumentu: Příspěvky z konference Konference/Akce: International Conference on Modern Electrochemical Methods (MEM) /36./, Jetřichovice (CZ), 20170523
Rok:
2016
Jazyk:
eng
Abstrakt: Here we describe the electrochemical behavior of a group of polyaromatics designated helicenes. These compounds are finding many applications in optoelectronics, catalysis and chiral separation. Thus it is important to investigate the electrochemical and optical behavior of helicenes with respect to improving their application potential and our knowledge of strategies for their surfaces immobilization. Electrochemical analyses were performed in acetonitrile and in aqueous media with glassy carbon and indium tin oxide electrodes. Specifically, [n]helicenes and their salts 1-buty1-3-(2-methy1[6]heliceny)-immidazolium bromide and 3-([7]helicene-9-y1)thiophene were investigated, the application of acquired electrochemical data is disussed, especially in terms of optoelectronics and the construction of semi-conductive devices.
Klíčová slova:
anodic reaction; electropolymerization; helicene Číslo projektu: BM1203 Poskytovatel projektu: COST Action EU-ROS Zdrojový dokument: XXXVI MODERNI ELEKTROCHEMICKE METODY, ISBN 978-80-905221-4-5 Poznámka: Související webová stránka: http://hdl.handle.net/11104/0277178
Práva: Dílo je chráněno podle autorského zákona č. 121/2000 Sb.