Original title: A Short Overview of the Electrochemistry of Helical Polyaromatics.
Authors: Vacek, J. ; Hrbáč, J. ; Zatlouklová, M. ; Storch, Jan
Document type: Papers
Conference/Event: International Conference on Modern Electrochemical Methods (MEM) /36./, Jetřichovice (CZ), 20170523
Year: 2016
Language: eng
Abstract: Here we describe the electrochemical behavior of a group of polyaromatics designated helicenes. These compounds are finding many applications in optoelectronics, catalysis and chiral separation. Thus it is important to investigate the electrochemical and optical behavior of helicenes with respect to improving their application potential and our knowledge of strategies for their surfaces immobilization. Electrochemical analyses were performed in acetonitrile and in aqueous media with glassy carbon and indium tin oxide electrodes. Specifically, [n]helicenes and their salts 1-buty1-3-(2-methy1[6]heliceny)-immidazolium bromide and 3-([7]helicene-9-y1)thiophene were investigated, the application of acquired electrochemical data is disussed, especially in terms of optoelectronics and the construction of semi-conductive devices.
Keywords: anodic reaction; electropolymerization; helicene
Project no.: BM1203
Funding provider: COST Action EU-ROS
Host item entry: XXXVI MODERNI ELEKTROCHEMICKE METODY, ISBN 978-80-905221-4-5
Note: Související webová stránka: http://hdl.handle.net/11104/0277178
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.

Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0277178

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