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The occurrence and interactions of iodine in a natural environment, focused on the hydrosphere.
ŠEDA, Martin
Iodine is an important element essential for higher animals. A large part of the global human population suffers from a lack of iodine; elucidation of transfer and mobility of this element in the environment, water, soil, air and in organisms is thus very important. The aim of this work was the elaboration and optimisation of the method for determination of very low concentrations of iodine in the waters. The mass spectrometry with inductively coupled plasma (ICP-MS) technique was used. It has been shown that using of different filter types during sample preparation had no significant effect on the content of impurities in the filtered sample. Antimony was recommended as an internal standard, despite commonly used elements (indium or tellurium). Samples were not preserved because nitric acid caused volatilization of iodine from the sample and the addition of aqueous ammonia had no significant effect. The optimised method was tested on several groups of water samples, including precipitation, surface water and lysimetric waters. From autumn 2009 to summer 2010, a part of the Blanice River (Šumava Mountains, South Bohemia) was sampled. The average content of iodine in samples ranged from 1.48 ? 0.30 ?g?dm-3 (April 2010) to 3.05 ? 0.38 ?g?dm-3 (July 2010). The average content of iodine in samples from all tributaries of the Blanice River ranged between 2.52 ? 1.63 ?g?dm-3 (March 2010) and 3.67 ? 1.37 ?g?dm-3 (July 2010). The concentration of iodine in the monitored surface waters did not change significantly along the flow of the river. The other two streams were sampled near Rapotín village (Jeseníky Mountains, north Moravia). The average contents of iodine were as follow: Annov (upper stream) 1.60 ? 0.65 ?g?dm-3, Annov (lower stream) 1.88 ? 1.18 ?g?dm-3, Salaš (upper stream) 1.77 ? 0.92 ?g?dm-3, Salaš (lower stream) 1.42 ? 0.58 ?g?dm-3. Generally, the data showed that considering iodine, the area of Šumava had slightly higher levels than those observed in the Jeseníky Mountains. Precipitation collected in the South Bohemia (Arnoštov village and city of České Budějovice) and in Jeseníky (Rapotín) contained less iodine compared to surface waters, and rarely exceeded 3 micrograms per liter of water. The situation has changed in the spring of 2010, because of the occurrence of volcanic dust and ash over the Czech Republic. This volcanic cloud came from the sudden activity of the Eyjafjallajökull Volcano (Iceland). In the mentioned period, the contents of iodine in precipitation were increased several times at all sample collection sites. This is an indirect evidence that iodine could be released during volcanic eruptions and transferred over long distances through the atmosphere. It turned out that the wastewater treatment plant can eliminate iodine in wastewater only partially. However, the wastewater treatment plants in the monitored region were too small to evaluate the overall impact on the environment. The maximum iodine content at the outlet of the wastewater treatment plant Prachatice town (South Bohemia) was 28.5 ?g?dm-3, which is several times higher than natural levels in the Živný stream, to which the treated water flows. Lysimetric water samples were collected from lysimeters installed in three nearby plots in Arnoštov village (Šumava, South Bohemia). The highest concentrations of iodine were found on plot where cattle were grazed. These values were significantly higher (average 4.38 ? 1.74 ?g?dm-3) than those obtained from a site used as hay meadow (average 2.69 ? 1.19 ?g?dm-3) or an untreated meadow (average 2.25 ? 1.39 ?g?dm-3). Iodine therefore probably originated from the urine and feces of grazed cattle. This thesis contributes to the total knowledge of iodine, particularly to the part concerning determination of iodine in the hydrosphere.
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Atmospheric deposition of nitrogen and phosphorus in the Czech republic and round the world.
SUCHÁ, Jitka
This bachelor thesis is focused on the atmospheric deposition of nitrogen and phosphorus in the Czech Republic and round the world. For easier understanding of atmospheric deposition in the thesis there are shortly explained terms such as the source of pollution, emissions and air pollutants, which are interdependent and often interact. There are presented different types of atmospheric deposition, their detailed classification, their collection and the process of determining the size of atmospheric deposition. Furthermore, this thesis gives the current value of atmospheric deposition in European and non European countries and the values in the Czech Republic, where the trend of atmospheric deposition from the fifties to the present is shortly described. The thesis presents the station network in the Czech Republic, its functions and methods of data collection, which are still used to evaluate the air quality situation in Europe in the EMEP programme, where you can find information about other European countries. Then the values of atmospheric deposition of nitrogen and phosphorus in the U.S., especially on the east coast and central parts of the United States of America, and China are presented. The last part of the thesis is focused on atmospheric nitrogen deposition value development in the Czech Republic selected, more or less affected areas in the Czech republic.
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Specifics of marketing communication in the Czech Republic
SUCHÁ, Věra
In order to have successful television advertising spot, it is important to define the specifics typical for the product which are acceptable in the country where the spot will air. The purpose of coffee as a product is to appeal to senses and to whet the appetite, preferably in a good company where peace, joy and pleasant atmosphere dominates. The important part of an advertising spot is also demonstration of drinking and preparing coffee so that the consumer can learn how to prepare coffee properly. This product has clearly delimited target audience. In case of instant coffee, the target audience, are men and women from 25 to 35 years. On the other hand, ground coffee is appreciated by men and women in their forties.
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Sediment disintegration due to air compressed by capillarity: overlooked erosion mechanism
Vaculíková, Jana ; Bruthans, Jiří (advisor) ; Kostkanová, Vladislava (referee)
Cílem této práce bylo orientačně otestovat, do jaké míry je rozpad díky vzduchu stlačovanému kapilární vodou nasávanou do sedimentu (kapilárně-pneumatický rozpad, KP rozpad) významným procesem při erozi různých sedimentů, jako jsou písky až slabě cementované pískovce, spraše, jíly, jílovce a případně i jílovité půdy. Dílčím cílem bylo především vytvořit a na několika vybraných materiálech otestovat jednoduchou metodiku, prokazující, zda sediment podlehne KP rozpadu, dále vypočítat destrukční tlak daný KP rozpadem v pórech sedimentu a porovnat ho s tahovou pevností materiálu a konečně posoudit vliv mineralogie a porosity sedimentů na KP rozpad. Pro odlišení KP rozpadu od jiných destrukčních procesů jsem zvolila pozorování rozpadu dvojic vzorků, kdy jeden byl saturován za běžného atmosférického tlaku vzduchu a druhý ve vakuu. Tato metoda je schopná odlišit KP působení od jiných erozních procesů a zároveň je přiměřeně rychlá a vhodná pro různé sedimenty a zeminy. Pozorování potvrzuje, že KP působení je schopno rozložit různé sedimenty a zeminy na jemné částice, jedná se o velmi důležitý proces rozpadu, který probíhá i ve stojaté vodě, může být iniciátorem pipingu a měl by být proto intenzivně studován. Srovnání vypočtených hodnot pórového tlaku s tahovou pevností ukázala, že vypočtené pórové tlaky...
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Different reaction of cultivars poppy seeds after nonthermal plasma treatment
Banulescu, G. ; Gajdová, Iveta ; Šerá, Božena ; Kuchtová, P. ; Šerý, M. ; Špatenka, P. ; Hnatiuc, E.
The influence of low-temperature atmospheric plasma treatment generated between the electrodes (GlidArc) on poppy seed growth was tested. Treatment times were 0 s, 180 s, 300 s, and 600 s. Working gas was air. We monitored germination and initial growth of two cultivars of poppy seeds (Papaver somniferum L., cultivars Major and Orfeus). The values of control measurements (exposure time 0 s) of the tested cultivars were different. Therefore we analysed both cultivars separately with adequate control during the data procesing. A positive influence was found mainly in the lengths of sprouts in cultivar Major (22 %, time 180 s). The number of germinated seeds was not affected by plasma treatment in both cultivars.
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Variability of the Brewer-Dobson Circulation
Kupčihová, Zuzana ; Pišoft, Petr (advisor) ; Kozubek, Michal (referee)
The middle atmosphere transport is mostly controlled by a large-scale meridional circulation, namely the Brewer-Dobson circulation. In this thesis, climatology and variability of the Brewer-Dobson circulation and the middle atmosphere has been analysed using the Canadian Middle Atmosphere Model (CMAM30-Ext). A number of key variables are used including the age of air, residual velocities, residual stream function, temperature and zonal wind. The analysis of the climatology of the age of air shows, in particular, that young air gets generated near the tropical tropopause, which then travels poleward. The residual stream function shows that the Brewer-Dobson circulation dominates the winter hemispheres around the solstices and becomes nearly symmetrical, with respect to the equator, around the equinoxes. The empirical orthogonal function analysis is applied to explore the modes of variability in the middle atmosphere. The analysis identifies, in particular, the semi-annual oscillation, the quasi-biennial oscillation with moderate explained variance compared to the variance explained by the annual cycle. In addition, the analysis also reveals the emergence of the solar cycle. Powered by TCPDF (www.tcpdf.org)
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Precision displacement interferometry with stabilization of wavelength on air
Lazar, Josef ; Holá, Miroslava ; Hrabina, Jan ; Buchta, Zdeněk ; Číp, Ondřej
We present an interferometric technique based on differential interferometry setup for measurement in the subnanometer scale in atmospheric conditions. The motivation for development of this ultraprecise technique is coming from the field of nanometrology. The key limiting factor in any optical measurement are fluctuations of the refractive index of air representing a source of uncertainty on the 10'6 level when evaluated indirectly from the physical parameters of the atmosphere. Our proposal is based on the concept of overdetermined interferometric setup where a reference length is derived from a mechanical frame made from a material with very low thermal coefficient on the 1 O'8 level. The technique allows to track the variations of the refractive index of air on-line directly in the line of the measuring beam and to compensate for the fluctuations. The optical setup consists of three interferometers sharing the same beam path where two measure differentially the displacement while the third represents a reference for stabilization of the wavelength of the laser source. The principle is demonstrated on an experimental setup and a set of measurements describing the performance is presented.
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Influence of atmosphere on small punch testing of P91 steel
Dymáček, Petr ; Dobeš, Ferdinand
The small punch testing (SPT) under constant force condition was performed in various atmospheres: air, hydrogen and argon. The material selected for the study was P91 steel and testing temperature 873 K. The effect of atmosphere on the test results such as time to rupture, minimum deflection rate and other parameters was measured and evaluated. The results show that there is not very strong but definite effect of atmosphere on SPT creep rupture time. The longest times to rupture were obtained in hydrogen atmosphere for whole range of tested forces. However the difference between tests in hydrogen and tests in air or in argon diminished with decreasing force and longer time to rupture.
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The smart electronic unit for precise measurement of refractive index of air in a nano-positioning stage for scanning probe microscopy (SPM)
Hucl, Václav ; Čížek, Martin ; Buchta, Zdeněk ; Mikel, Břetislav ; Lazar, Josef ; Číp, Ondřej
When the traceable measurement of dimensions of samples in scanning probe microscopy is needed the position of the probe tip has to be monitored by a set of laser interferometers. The measurement is done very often during standard atmospheric conditions so the changes of the refractive index of air have an influence to measured values of the length with 1.0exp(-4) relatively. Thus the measurement of the refractive index of air and application of the instantaneous value of the index to all of measurement interferometric axes is necessary. In the work we developed new concept of electronic unit which is able to monitor the refractive index of air on basis of measurement of weather conditions: temperature, humidity and pressure of the air. The unit uses modified Edlen formula for calculation of the refractive index. The next step of the work is verification of accuracy of the measuring capability of the unit. We tested the accuracy with reference unit which measure the refractive index of air by a set of etalon sensors. The expected accuracy of the smart electronic unit falls to the 4.1exp(-7) relatively. The important advantage of the unit is very low power consumption of electronics so the unit causes very small temperature effects to the measuring process.
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