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Polymer composites with controlled interphase
Zvonek, Milan ; Knob, Antonín (referee) ; Čech, Vladimír (advisor)
Cieľom diplomovej práce je príprava polymerných kompozitov vyztužených sklenenými vláknami s riadenou medzifázou za použitia metódy plazmochemickej depozície z plynnej fáze a monomeru tetravinylsilanu. Teoretická časť je zameraná na literárnu rešerš o plazme, plazmovej polymerácií, tenkých vrstvách a kompozitoch. Experimentálna časť popisuje použité materiály a aparaturu použitú na povrchovú modifikáciu sklenených vlákien a prípravu vláknom vyztužených kompozitov. Povrchová úprava sklenených vlákien prebiehala za rôznych depozičných podmienok. Chemické a mechanické analýzy vytvorenej medzivrstvy prebiehali za použitia FTIR spektrometrie a vrypového testu. Vliv povrchovej úpravy bol zistený pomocou získanej interlaminárnej šmykovej sily použítím testu krátkych trámečkov.
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Surface modification of glass fibers using plasma nanotechnology
Sedlák, Filip ; Knob, Antonín (referee) ; Čech, Vladimír (advisor)
Diploma thesis is aimed at deposition of thin films on glass fibers using plasma-enhanced chemical vapor deposition from tetravinylsilane as a monomer. Such surface modified glass fibers were used as reinforcements for fabrication of polymer composites with unsaturated polyester resin as a matrix. Chemical and optical properties of prepared thin films were characterized using infared spectroscopy and spectroscopic ellipsometry. An influence of deposited thin films on the shear strength of composite material was observed using short-beam shear test.
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Surface modification of glass fibers for polymer composites
Knob, Antonín ; Marek,, Aleš (referee) ; Burša, Jiří (referee) ; Čech, Vladimír (advisor)
The doctoral thesis is aimed at preparation of glass fiber reinforced polymer composites with controlled interphase formed by plasma-polymerized tetravinylsilane and tetravinylsilane/oxygen thin films. The thin polymer films of specific physico-chemical properties and thickness were deposited to improve interfacial adhesion of glass fiber/polyester composites. The fiber surface modification was performed by using plasma enhanced chemical vapor deposition in low-temperature RF plasma operating in an various effective power range and different treatment time. Test results were examined in relation to the interlayer thickness and different treatment conditions. The prepared interlayers were analyzed to evaluate physico-chemical composition and properties (XPS, RBS, ERDA, FTIR and spectroscopic elipsometry). Selected mechanical properties were evaluated by AFM. Mechanical response of plasma interlayers was evaluated by short beam shear test and direct method of testing the interfacial shear strength using microindentation. The interphase shear failure was controlled by the shear strength at the interlayer/fiber interface as follows from experimental and model data.
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City House – Mixet Use Architecture
Martochová, Jana ; Ing.arcg.Pavel Šimeček (referee) ; Menšíková, Naděžda (advisor)
The theme of my disseration is an architecture study of multifunctional building which is surrounded by the streets Vranovská, Cejl and Jana Svobody and by the embankment of the river Svitava. Objective of the study was to design a building that would utilized the space of the plot effectively. The result of design is the construction which is characterized for its inner semi-public atrium space with link to the bank of Svitava and street Jana Svobody. It is five-storey house. In the first two stories there are different feature amenities (kindergarden, office building, restaurant, café, media library, gallery and other shops), and senior house. In the third floor and above there are designed flats for living. The part of the living area was also creating of new kind of housing called co-housing. The building has a basement, which is mostly for parking. The construction of the building is from monolithic reinforced concrete frame, horizontal structure consists of beamless slabs. Due to the huge area of the building, the facade is designed from the different kinds of materials: white plaster, light gray sheet metal, anthracite metail mesh and glass fiber.
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Pultrusion process optimizing of composites based on epoxy matrix
Ostrezi, Jan ; Bábík, Adam (referee) ; Přikryl, Radek (advisor)
The theoretical part of this bachelor thesis deals with current progress in the field of long fibre reinforenced composites with matrix based on epoxy resins. It also deals with production methods of composite materials, especially pultrusion. The practical part is based on pultrusion process optimizing of composites profiles based on epoxy matrix. Profiles were examined by DMA test to set the glass transition temperature.
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The influence of surface modification of glass fibers on mechanical response of the GF/polyester composite
Janeček, Pavel ; Richtera, Lukáš (referee) ; Čech, Vladimír (advisor)
The diploma thesis is aimed at an influence of surface modifications of fibrous reinforcements on mechanical properties at the fiber-matrix interface in fiber reinforced composites. Glass fibers were used as reinforcements and polyester resin was the matrix. The sample of composite consisted of polymer matrix in a form of cylindrical body placed on bundle of glass fibers. The design of the sample was constructed with respect to results of Finite Element Analysis (FEA). The tensile test using a materials testing machine (Zwick) was employed to evaluate adhesion at the fiber-matrix interface. Untreated glass fibers, fibers with commercial sizing, and fibers modified by deposition of plasma polymer film using Plasma-Enhanced Chemical Vapor Deposition (PECVD) at different deposition conditions were used for fabrication of composite samples. The fibers and composite samples were analyzed by Scanning Electron Microscopy (SEM) and Confocal Laser Scanning Microscopy (CLSM).
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Fiber reinforcements for polymer composites
Knob, Antonín ; Grégr, Jan (referee) ; Čech, Vladimír (advisor)
The bachelor thesis is concerned with an influence of surface modification of fibrous reinforcements on mechanical properties at the fiber-matrix interface in fiber-reinforced polymer composites. Polyester resin was used as a matrix, glass and carbon fibers were the reinforcements. The composite sample consisted of polymer matrix in a form of cylindrical body placed on a bundle of fibers. Untreated fibers and fibers with a commercial sizing were used for fabrication of composite samples. The tensile test using a materials testing machine (Zwick) was employed to evaluate adhesion at the fiber-matrix interface.
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Preparation of glass fiber/polyester composites
Horská, Pavlína ; Richtera, Lukáš (referee) ; Čech, Vladimír (advisor)
The bachelor thesis is aimed at an influence of surface modifications of fibrous reinforcements on mechanical properties at the fiber-matrix interface in fiber reinforced composites. Glass fibers were used as reinforcements and polyester resin was the matrix. The sample of composite consisted of polymer matrix in a form of cylindrical body placed on a bundle of glass fibers. The tensile test using a materials testing machine (Zwick) was employed to evaluate adhesion at the fiber-matrix interface. Untreated glass fibers and fibers with commercial sizing were used for fabrication of composite samples.
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