|
|
Suitability of vitrified lignite bottom ash for composite cements.
Bayer, Petr ; Krátký, Josef (referee) ; Wolter, Albrecht (advisor)
Předložená magisterská práce se zabývá možným použitím vitrifikovaného lignitového lóžového popele jako náhrada slinku v kompozitních cementech. Byly zkoumány vlivy přidaného vitrifikovaného lóžového popele, jeho jemnosti, alkalických roztoků a jejich koncentrací. Byly připraveny kompozitní cementy v souladu s normou DIN EN 197 – 1. V těchto cementech bylo nahrazeno 30 % slinku vitrifikovaným lóžovým popelem. Konkrétně byly připraveny kompozitní cementy s vitrifikovaným lóžovým popelem o jemnosti 5549 cm2/g a 8397 cm2/g. Dále byly přidány alkalické roztoky hydroxidů a síranů vždy o dvou různých koncentracích, za účelem stimulace pucolánové a/nebo geopolymerní reakce. Mechanické vlastnosti připravených vzorků byly charakterizovány mechanickým testováním na prizmách s rozměry 40×40×160 mm, jak je specifikováno v normě DIN EN 196 – 1. Byla provedena nedestruktivní měření dynamického elastického modulu a destruktivní testovaní na pevnosti v tlaku a v ohybu. Distribuce velikosti částic a chemická analýza vstupních materiálů byla vykonána pomocí laserové granulometrie a rentgenové fluorescence. U zatvrdlých kompozitů bylo dále zkoumáno po 2 a 28 dnech hydratace fázové složení s využitím metody rentgenové difrakce a mikrostruktura s využitím skenovací elektronové mikroskopie. Výsledky ukázaly, že mechanické vlastnosti jsou nezávislé na množství přidaných alkálií stejně jako na jemnosti přidaného vitrifikovaného lóžového popele. Nicméně, znatelně nižší mechanické pevnosti byly pozorovány pro vzorky, které byly aktivovány hydroxidy, pravděpodobně kvůli brzké tvorbě silikátového hydrogelu. Vzorky aktivované sírany nedosáhly pevností jako referenční malta.
|
|
|
Modification of silicate materials for floors
Šlechtický, Luboš ; Ing. Miroslav Šťenko, Ph.D., LB Cemix (referee) ; Šťastník, Stanislav (advisor)
The thesis is devoted to the issue of flooring materials, cement and plaster. In the first part are discussed general properties and general requirements for flooring, as well as presents the most important properties of selected flooring materials. The work is dedicated to the modulus of elasticity, adhesion to the substrate and strength parameters of the tested materials. It also evaluates the effects of redispersible polymer powders in silicate compositions intended for floors.
|
|
|
The study of the influence of the composition of the lightweight fiber concrete physical and mechanical properties
Šindelek, David ; Bodnárová, Lenka (referee) ; Hela, Rudolf (advisor)
This bachelor thesis deals with a study of light construction concrete with an addition of steel fibre which monitors its impact of the physical mechanical properties. The work is divided into two parts, theoretical and practical. The theoretical part is focused on characteristics and a design of light concrete within the class 35MPa and over with the density within the class of D1,8. Furthermore, it focuses on the increase of toughness of cementitious composites with the form of application of steel fibre in different doses and lengths. In the practical part, formulas of two strength classes 35/38 D 1,8 and 45/50 D1,8 were designed with the help of the steel fibre Krampeharex in doses of 25 and30 kg/m3, and where there were both its impact of the working diagram as well as the compressive strength monitored for the duration of twenty-eight days
|
|
| |
|
|
The admixtures which are influencing setting time of portland cement
Hlaváček, Jaroslav ; Kalina, Lukáš (referee) ; Opravil, Tomáš (advisor)
During the production of concrete is important the careful selection of raw materials. Nowadays, we are trying in the production to minimize the economic burden and to maximize the use of secondary raw materials. This work is focused on the use of secondary raw materials from the energy industry in construction for the preparation of hydraulic binders. As the main raw materials were used different power plant fly ash from fluidized combustion. The composition of these secondary materials is quite different from conventional high-temperature ash, due to mixing with water they solidify and harden. Experiments were performed with three lodge fly ash from electrostatic precipitators of the fluidized combustion and one high-temperature fly ash. This work is focused on the possibility of monitoring the use of these secondary materials in construction, especially when tests were evaluated characteristics of strength and speed of setting and hardening.
|
|
| |
|
|
Methodology of historical bricks and masonry tests
Bartoň, Vojtěch ; Anton, Ondřej (referee) ; Cikrle, Petr (advisor)
This diploma thesis is focused on methodology for sorting of solid fired bricks for reconstruction of historical buildings. The theorethical part of this thesis includes description of production technology of solid fired bricks and diagnostic methods. In practical part there are these methods aplied on the solid fired bricks, which are intended for reconstruction of the bridge in Sedlec. There are monitored changes in structure of solid fired bricks caused by repeated freezing and defrosting. This changes are monitored by resonant frequency method and ultasonic pulse method.
|
|
|
The effect of particles size on the properties of mortars.
Sehnal, Tomáš ; Krátký, Josef (referee) ; Šiler, Pavel (advisor)
The consumption of concrete as a building material is still increasing over the world. Concrete production is closely associated with CO2 and other greenhouse gases emissions. The reduction of these emissions can be achieved by a higher utilization of secondary raw materials in cement mixtures. This bachelor work is focused on the using of secondary raw material, finely ground granulated blast furnace slag and fly ash from fluidized bed combustion and high temperature combustion. The properties of milling pure cement and cement mortars with addition of secondary raw material will be measured. Compressive strength, flexural strength, and calorimetric measurement will be performed for these prepared mortars.
|
|
|
Geopolymers based on fly ashes and brick body
Řezník, Bohuslav ; Lang,, Karel (referee) ; Příhoda,, Jiří (referee) ; Žižková, Nikol (referee) ; Rovnaníková, Pavla (advisor)
In line with the current focus on utilizing side products of various production processes, this dissertation thesis analyzes the process of alkali activation of particular side products: fly ash and brick fragments. This activation produces geopolymeric materials widely used in civil engineering. The thesis aims to optimize the geopolymerization process so that the resulting geopolymer is both ecologically and economically viable. To that end, the thesis studies the course of geopolymeric reaction between the alkali activator and fly ash from: (i) the Chvaletice power plant, (ii) the Dětmarovice power plant, and (iii) biomass combustion, as well as (iv) fluid fly ash from the Hodonín power plant. All experiments of geopolymeric reaction have focused on the factors influencing the synthesis of geopolymers—that is: composition of the alkali activator, the ratio of alumino-silicate to the activator, and the impact of temperature on structure of the synthesized geopolymer. Further, the thesis analyzed the synthesized polymer’s microstructure, phase composition, resistance against corrosive conditions, and compressive strength, as well as mechanical-fracture properties of selected fly-ash geopolymers. The thesis finds that the most suitable for geopolymeric synthesis appears to be the fly ash from the Chvaletice power plant in which case the obtained geopolymers showed best properties in the studied areas. The fly ash from the Dětmarovice power plant, biomass fly ash, and fluid fly ash have failed to reach acceptable properties. Separately, the thesis studies the geopolymerization of brick body that could be suitable input for alkali activation. The geopolymers synthesized from brick fragments resulted in materials of supperior mechanical strength. A mixed use of fly ash and brick fragments failed to show a synergetic effect. Properties of the resulting geopolymers have been inferior to the properties of geopolymers produced using just fly ash or just brick body.
|
|
|
The study of the refractory concrete binding system based on phosphoric acid and aluminous cement
Pavlík, Tomáš ; Švec, Jiří (referee) ; Šiler, Pavel (advisor)
This thesis deals with refractory concrete binding system based on aluminous cement and phosphoric acid. The prepared refractory concretes were fired at 1 000 °C. Various effects on compressive strength of refractory concrete were studied. The influence of aluminous cement content and phosphoric acid content, the influence of various admixtures, the influence of plasticizers and the influence of time and method of sample storage were studied. Simultaneous thermogravimetry and differential thermal analysis of the basic unfired sample were performed. Finally, selected refractory concretes were fired at 110, 200, 400, 600, 800, 900, 1 000 and 1 100 °C. The compressive strength of these samples was measured and powder X ray diffraction analysis was performed. The compressive strength of refractory concretes under intermediate temperatures (800–1 100 °C) was most increased in samples with metakaolin and gray microsilica.
|
guest ::
