Název: Phase equilibria of carbon dioxide and methane gas-hydrates predicted with the modified analytical S-L-V equation of state
Autoři: Vinš, Václav ; Jäger, A. ; Hrubý, Jan ; Span, R.
Typ dokumentu: Příspěvky z konference
Konference/Akce: Experimental Fluid Mechanics 2011, Jičín (CZ), 2011-11-22 / 2011-11-25
Rok: 2011
Jazyk: eng
Abstrakt: Gas-hydrates (clathrates) are non-stoichiometric crystallized solutions of gas molecules in the metastable water lattice. Two or more components are associated without ordinary chemical union but through complete enclosure of gas molecules in a framework of water molecules linked together by hydrogen bonds. The clathrates are important in the following applications: the pipeline blockage in natural gas industry, potential energy source in the form of natural hydrates present in ocean bottom, and the CO2 separation and storage. In this study, we have modified an analytical solid-liquid-vapor equation of state (EoS) [A. Yokozeki, Fluid Phase Equil. 222–223 (2004)] to improve its ability for modeling the phase equilibria of clathrates. The EoS can predict the formation conditions for CO2- and CH4-hydrates. It will be used as an initial estimate for a more complicated hydrate model based on the fundamental EoSs for fluid phases.
Klíčová slova: aqueous solutions; equation of state; gas-hydrate
Číslo projektu: CEZ:AV0Z20760514 (CEP), GAP101/11/1593 (CEP), GPP101/11/P046 (CEP)
Poskytovatel projektu: GA ČR, GA ČR
Zdrojový dokument: International Conference Experimental Fluid Mechanics 2011, ISBN 978-80-7372-784-0

Instituce: Ústav termomechaniky AV ČR (web)
Informace o dostupnosti dokumentu: Dokument je dostupný v příslušném ústavu Akademie věd ČR.
Původní záznam: http://hdl.handle.net/11104/0006705

Trvalý odkaz NUŠL: http://www.nusl.cz/ntk/nusl-80947


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Věda a výzkum > AV ČR > Ústav termomechaniky
Konferenční materiály > Příspěvky z konference