Original title: Photochemical Synthesis of Aza-aromatic Compounds.
Authors: Kos, Martin ; Žádný, Jaroslav ; Storch, Jan ; Sýkora, Jan ; Církva, Vladimír
Document type: Papers
Conference/Event: Advances in Organic, Bioorganic and Pharmaceutical Chemistry Liblice 2017 /52./, Lázně Bělohrad (CZ), 20171103
Year: 2017
Language: eng
Abstract: Herein we report synthesis of series of novel both aza- and diaza-helicenes, and phenacenes, which were prepared mainly by photocyclization of corresponding imine precursors. Reaction conditions of photocyclization (i.e. solvent, photocatalyst, type of irradiation, use of water scavenger) were optimized and enhanced. Usage of TEMPO as oxidizing agent leads to improvement of yields up to 72 %. Prepared 2-pyridyl substituted azaphenacenes will be utilized for preparation of potential semiconductive layers in cooperation with IMC of the CAS.
Keywords: azaphenacenes; photocyclization; polyaromatics
Project no.: GA15-12719S (CEP), GA17-02578S (CEP)
Funding provider: GA ČR, GA ČR
Host item entry: Book of Abstracts, ISBN N.
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.

Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0277641

Permalink: http://www.nusl.cz/ntk/nusl-369653


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