Original title:
Potential-driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-derived Polymers.
Authors:
Žádný, Jaroslav ; Storch, Jan ; Strašák, Tomáš ; Církva, Vladimír ; Hrbáč, J. ; Fekete, Ladislav ; Pokorný, Jan ; Bulíř, Jiří ; Vacek, J. Document type: Papers Conference/Event: Advances in Organic, Bioorganic and Pharmaceutical Chemistry Liblice 2017 /52./, Lázně Bělohrad (CZ), 20171103
Year:
2017
Language:
eng Abstract:
3-([7]H elicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by cyclic voltammetry with anodic potential limits of +1.5 V or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations; UV-Vis, fluorescence and vibrational spectroscopies, ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics and sensing technologies.
Keywords:
anodic reaction; electrosynthesis; helicene Project no.: GA17-02578S (CEP) Funding provider: GA ČR Host item entry: Book of Abstracts, ISBN N.
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.