Original title: Ferrocene Oxidation; a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry
Authors: Jaklová Dytrtová, Jana ; Jakl, M. ; Schröder, Detlef
Document type: Papers
Conference/Event: Moderní elektrochemické metody /31./, Jetřichovice (CZ), 2011-05-23 / 2011-05-27
Year: 2011
Language: eng
Abstract: The coupling of ESI-MS with two-electrodes flowing cell was provided and tested on ferrocene system. The oxidation potential of ferrocene was 430 mV in Pt/Ag electrode system. The bis-coordinated ferrocene complex with base electrolyte (NaClO4) was found using DPASV provided in different accumulation potentials and its analogy was also observed as protonated cation in mass spectra. The impact of inserted accumulation potential on mass spectra was also studied; the inserted potential changes the natural pattern of ferrocene.
Keywords: base electrolyte; CV; DPASV; ESI-MS; ferrocene
Project no.: CEZ:AV0Z40550506 (CEP), GA203/08/1487 (CEP)
Funding provider: GA ČR
Host item entry: Sborník přednášek. XXXI. Moderní elektrochemické metody, ISBN 978-80-254-9634-3

Institution: Institute of Organic Chemistry and Biochemistry AS ČR (web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences.
Original record: http://hdl.handle.net/11104/0243314

Permalink: http://www.nusl.cz/ntk/nusl-180558


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Research > Institutes ASCR > Institute of Organic Chemistry and Biochemistry
Conference materials > Papers