Národní úložiště šedé literatury Nalezeno 2 záznamů.  Hledání trvalo 0.03 vteřin. 
Ferrocene Oxidation; a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry
Jaklová Dytrtová, Jana ; Jakl, M. ; Schröder, Detlef
The coupling of ESI-MS with two-electrodes flowing cell was provided and tested on ferrocene system. The oxidation potential of ferrocene was 430 mV in Pt/Ag electrode system. The bis-coordinated ferrocene complex with base electrolyte (NaClO4) was found using DPASV provided in different accumulation potentials and its analogy was also observed as protonated cation in mass spectra. The impact of inserted accumulation potential on mass spectra was also studied; the inserted potential changes the natural pattern of ferrocene.
Electrochemistry with Mass spectrometry as a Tool of Metal Complexes with Organic Ligand Studies
Jaklová Dytrtová, Jana ; Jakl, M. ; Schröder, Detlef
Electrochemical and mass spectrometric approaches for the detection of metals species with organic ligands are compared. Advantages of the connection of electrochemistry with mass spectrometry are discussed.

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