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Original title:
Multiple Sulfidation/Regeneration Cycle Tests for Advanced Fuel Conversion Process by 20 wt%Fe2O3/Al2O3 Sorbent
Authors: Huang, C.Y. ; Chyou, Y.P. ; Svoboda, Karel
Document type: Papers
Conference/Event: International Congress of Chemical and Process Engineering /21./ - CHISA 2014 and Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction /17./ - PRES 2014, Prague (CZ), 2014-08-23 / 2014-08-27
Year: 2014
Language: eng
Abstract: In this study, 20 wt%Fe2O3/Al2O3 was used as a sorbent to perform multiple sulfidation/regeneration cycle tests in a fixed-bed reactor under simulated hot syngas conditions. The physical properties of sorbents were analyzed by X-ray diffraction (XRD), inductively coupled plasma atomic emission spectrometry (ICP-AES), BET, and SEM/EDS. ICP-AES results indicated that the composition of metal oxide was close to the theoretical value. Multiple sulfidation/regeneration cycle tests showed that the 20wt%Fe2O3/Al2O3 can be regenerated and thus reused after the oxidation process. Due to the sulfidation reaction, colour change of the 20 wt%Fe2O3/Al2O3 sorbent was observed, from the original red to black. After six sulfidation-regeneration cycles, the sulfur capacity of the sixth cycle remained approximately on a level of 68% of the sulfur capacity in the first cycle. The BET analysis showed that the surface area decreased as the cycle number increased. The sulfidation-regeneration cycles were coupled with endothermic-exothermic reactions, which probably caused sintering of the sorbent, decreasing its surface area and sulfur capacity.
Keywords: fixed-bed reactor; silfidation reaction; sorbent
Project no.: GA14-09692J (CEP), 103-2923-E-042A-001-MY3
Funding provider: GA ČR, NSC
Host item entry: Final program, ISBN 978-80-02-02555-9
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.
Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0236029
Permalink: http://www.nusl.cz/ntk/nusl-175034
The record appears in these collections:
Research > Institutes ASCR > Institute of Chemical Process Fundamentals
Conference materials > Papers
Authors: Huang, C.Y. ; Chyou, Y.P. ; Svoboda, Karel
Document type: Papers
Conference/Event: International Congress of Chemical and Process Engineering /21./ - CHISA 2014 and Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction /17./ - PRES 2014, Prague (CZ), 2014-08-23 / 2014-08-27
Year: 2014
Language: eng
Abstract: In this study, 20 wt%Fe2O3/Al2O3 was used as a sorbent to perform multiple sulfidation/regeneration cycle tests in a fixed-bed reactor under simulated hot syngas conditions. The physical properties of sorbents were analyzed by X-ray diffraction (XRD), inductively coupled plasma atomic emission spectrometry (ICP-AES), BET, and SEM/EDS. ICP-AES results indicated that the composition of metal oxide was close to the theoretical value. Multiple sulfidation/regeneration cycle tests showed that the 20wt%Fe2O3/Al2O3 can be regenerated and thus reused after the oxidation process. Due to the sulfidation reaction, colour change of the 20 wt%Fe2O3/Al2O3 sorbent was observed, from the original red to black. After six sulfidation-regeneration cycles, the sulfur capacity of the sixth cycle remained approximately on a level of 68% of the sulfur capacity in the first cycle. The BET analysis showed that the surface area decreased as the cycle number increased. The sulfidation-regeneration cycles were coupled with endothermic-exothermic reactions, which probably caused sintering of the sorbent, decreasing its surface area and sulfur capacity.
Keywords: fixed-bed reactor; silfidation reaction; sorbent
Project no.: GA14-09692J (CEP), 103-2923-E-042A-001-MY3
Funding provider: GA ČR, NSC
Host item entry: Final program, ISBN 978-80-02-02555-9
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.
Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0236029
Permalink: http://www.nusl.cz/ntk/nusl-175034
The record appears in these collections:
Research > Institutes ASCR > Institute of Chemical Process Fundamentals
Conference materials > Papers
Record created 2014-09-11, last modified 2023-12-11
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