Original title:
Use of the Silver Solid Amalgam Electrode for Determination of 5-Nitroindazole
Authors:
Nováková, Kateřina ; Navrátil, Tomáš ; Hrdlička, V. ; Vyskočil, V. ; Barek, J. ; Chýlková, J. Document type: Papers Conference/Event: Moderní Elektrochemické Metody /34./, Jetřichovice (CZ), 2014-05-19 / 2014-05-23
Year:
2014
Language:
eng Abstract:
The voltammetric behavior of 5- nitroindazole (5-NI) has been investigated using mercury meniscus modified (m-AgSAE) silver solid amalgam electrode (inner diameter 0.5 mm). Differential pulse voltammetry (DPV) and cyclic voltammetry (CV) were used for study of electrochemical behavior of 5-NI. Britton-Robinson buffer was found to be the best available supporting electrolyte for 5-NI determination. The reaction mechanism was investigated by CV and by elimination voltammetry with linear scan (EVLS). DPV with optimized working parameters was applied for analysis of model solutions containing 5-NI. The limit of detection was calculated as 0.14 mol L for m-AgSAE. Proposed method was successfully tested for analysis of real water samples spiked by 5-NI.
Keywords:
5-nitroindazole; Silver solid amalgam electrode; Voltammetry Project no.: GAP208/12/1645 (CEP) Funding provider: GA ČR Host item entry: Sborník přednášek mezinárodní odborné konference XXXIV. Moderní Elektrochemické Metody, ISBN 978-80-905221-2-1
Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR
(web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences. Original record: http://hdl.handle.net/11104/0234059