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Energy balance in wastewater treatment plants
Novotný, Jan ; Raclavský, Jaroslav (referee) ; Hluštík, Petr (advisor)
This masters thesis is dealing with energetic evaluation of selected municipal WWTP – WWTP Polička. First chapter, introduction explains basic terms and goals of thesis. Second chapter explains energy audit, energy audit process its scope and contents. Third chapter deals with assesing life cycle using LCA (life cycle assesment). Fourth chapter deal with energy consumption at WWTP in Czech Republic as well as in the world. Fifth chapter describes technology of WWTP Polička and its fundamental objects. Sixth chapter is assesment of WWTP Polička from hydraulic point of view and assesment of selected machinery. Further there is summation of capital and operational costs followed by capital investment return.
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Distribution of pharmaceuticals in wastewater treatment plants
Šilhánková, Lenka ; Čáslavský, Josef (referee) ; Vávrová, Milada (advisor)
This bachelor’s thesis deals with a trending topic – wastewater distribution of pharmaceuticals proven to be toxic to non-target organisms – specifically, the occurrence of beta-blockers, plentifully used in treating hypertension and other cardiovascular diseases, is discussed. Members of this group, Atenolol, Acebutolol and Bisoprolol were chosen for closer study. The elimination of these chemicals was observed in three wastewater treatment plants (WWTP) with different treatment technologies and various number of population equivalents. For said analytes, UHPLC with UV/VIS detection using diode array detector (DAD) method was optimalised. A part of this thesis also deals with optimalization of isolation and concentrating the analytes. Unfortunately, the described method was not suitable for real sample analysis, because in most samples, the limit of quantification or even the limit of detection was not exceeded. It would be best for an analytical method with higher sensitivity, e. g. mass detector, to be used. The data gained in this experiment do not hold any informational value about the effectiveness of WWTP, as the exact amount of Acebutolol in effluent was measured only in one case. Based on the to-date executed analysis, it is impossible to conclude whether the quality of the treated water, concerning the content of aforementioned pharmaceuticals, is in any way ideal.
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Removal of antibiotics from wastewater by advanced oxidation technologies
Macsek, Tomáš ; Rusník,, Igor (referee) ; Bodík,, Igor (referee) ; Hlavínek, Petr (advisor)
Antibiotics are substances that inhibit the growth of microorganisms and are widely used in modern medicine. High consumption of antibiotics correlates with their elevated occurence in sewage systems, from where they are further released into the environment. The threat of their occurrence in the environment is in triggering the formation and spread of antibiotic resistance. This thesis focuses on the removal of selected antibiotics and partly on the antibiotic resistance from wastewater by advanced oxidation processes (AOPs). AOPs are based on the creation of highly reactive hydroxyl radicals, which are able to oxidize even highly persistent substances. The thesis focuses on the purification of effluents from municipal wastewater treatment plants (WWTP), which are identified as the main source of pharmaceutical pollution in the environment, by AOPs mainly based on ozonation. These processes were tested under laboratory conditions on model water as well as under real conditions as the tertiary stage of the treatment at Brno-Modřice WWTP under various operating states. As the results of the performed experiments show, it could be concluded that the studied AOPs are capable of effective degradation of studied antibiotics from the treated medium. Under real conditions, the antibiotics sulfamethoxazole, trimethoprim, azithromycin and clarithromycin were monitored. Output concentrations in each operational state were achieved to be below the limit of detection for all four antibiotics. The application of AOPs based on ozonation as the tertiary step of the treatment also had a positive effect on the reduction of microbial contamination and antibiotic resistance. Within the pilot plant experiments, a reduction of up to 4 orders of magnitude of E.coli, coliform microorganisms and a reduction of their resistant strains in the range of 1.4 - 4.0 logs were observed, compared to the effluent from the WWTP.
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Determination of linear synthetic aromatic compounds in abiotic and biotic matrices
Tulková, Tereza ; Čáslavský, Josef (referee) ; Vávrová, Milada (advisor)
Synthetic musk compounds are artificial organic compounds with a smell similar to the odor of a natural musk. The most recently discovered and also the least known group of artificial musks is linear musk compounds. These substances are now often used in cosmetics, personal care products, detergents and various cleaning products. They have leaked into all the major environment components, especially into the hydrosphere. There has been great attention drawn to synthetic musk compounds in the last few years because of their environmental impact. The aim of this thesis is to identify twelve linear musk compounds (linalool, 2-cyclohexylethanol, fresco menthe, citronellol, HSA, isobornyl acetate, arocet, aroflorone, allyl cyclohexyl propionate, lilial, isoamyl salicylate and hexylcinnamic aldehyde) in waste water samples. The samples were taken at three different waste water treatment plants (WWTP) in South Moravian region (WWTP Brno-Modřice, WWTP Luhačovice and WWTP Hodonín). Each of these treatment plants has a different equivalent number of inhabitants. At first, a working method was optimized, then applied on real waste water samples. Solid-phase microextraction (SPME) technique was used for the extraction of analytes. Gas chromatography–mass spectrometry (GC/MS) was then used for identification and quantificaton of the studied compounds.
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Wastewater treatment plants for municipalities with gravitational inflow
Benešová, Irena ; Vachovec, Roman (referee) ; Hluštík, Petr (advisor)
Diploma thesis is aimed on description of wastewater treatment plant with gravitational inflow. Focus is on WWTP in the Czech Republic, particularly in the South Moravia region - in this aspect the thesis presents relevant statistics like the number of WWTP per region and the total, capacity of WWTP per region and their substance load on inflow /outflow. The recherche is also limited according to the core subject of theoretical part, which is technology of small WWTP in the category up to 2000 equivalent habitants. The experimental part presents comparsion of particular wastewater treatment plant of this category in the South Moravia region: one with gravitational inflow and one with inflow pump station. The examined wastewater treatment plant are compared according to substance load, hydraulic load and technology. Thesis is concluded with a review of the different operation parameters of the both types of WWTP.
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Solutions and variability of vertical filters
Roupec, Ladislav ; Hyánková, Eva (referee) ; Kriška-Dunajský, Michal (advisor)
The bachelor thesis deals with innovative technical solution of vertical trickle filter systems, which are categorized into the category of natural ways thow to clean water. The actual vertical filters for root cleaners are currently experiencing a boom thanks to the MPO project with the working title Biostream, within which are vertical root systems tested on root cleaner in the village of Kotenčice (involved in pilot conditions). The results show an increased removal of ammonia nitrogen and high efficiency in the elimination of organic pollution BSK5 and CHSKCr. However, the practice may in the future require even higher efficiency that can be solved by small technical innovations and modifications. In connection with the forced aeration of vertical filters is elaborated the methodological part of the thesis, the final result of the work is several regression equations using which it is possible to determine the input of oxygen into the system at a given input parameters (filter size, water flow, air flow, etc.). The results are very useful for a scientific branch because there is not so much available literature for this topic.
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Comparison of mechanical and biological wastewater treatment plants in terms of financial costs and environmental impact
Winkler, Ondřej ; Výskala, Miloslav (referee) ; Aigel, Petr (advisor)
The aim of this bachelor thesis is to analyse and compare the operating costs and quality of water discharged at mechanical-biological and root wastewater treatment plants. In the first part, the bachelor thesis deals with theoretical knowledge in the field of wastewater treatment. There is legislation related to WWTPs, types, quantities, and transport of wastewater, it also describes the process and technology of water treatment and, finally, the management of waste generated during treatment and its treatment. The following chapters are devoted to economic indicators of wastewater treatment plants as well as pollution indicators. This part forms the transition between the theoretical and practical part of the bachelor thesis. We will learn here what are the costs of operating the treatment plant and how these costs will be reflected in the calculation of sewerage. We will also learn here which pollution indicators are measured as part of the quality of wastewater discharged from the WWTP. In the following part, the bachelor's thesis deals with the analysis and comparison of the already mentioned costs of operation and quality of discharged water at different types of wastewater treatment plants. The analysis was performed at four root and six mechanical-biological wastewater treatment plants in a total of four districts. The conclusion of the bachelor thesis belongs to the global comparison within the Czech Republic and the evaluation of the goals of the bachelor thesis.
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Study of Transfer of Musk Compounds in Abiotic and Biotic Components of Aquatic Ecosystems
Zouhar, Libor ; Hajšlová, Jana (referee) ; Sokol, Jozef (referee) ; Večeřa, Zbyněk (referee) ; Vávrová, Milada (advisor)
This work was focused on the determination of musk compounds in various components of the environment. Synthetic musk compounds are organic substances commonly used as fragrant constituents of detergents, perfumes, cosmetics and other personal care products (PCPs). These compounds contaminate the aquatic environment through municipal wastewater from sewage treatment plants. The result is accumulation of these analytes in the environment and their occurrence in food chain. Synthetic fragrances are commonly detected also in human body; these substances generally belong among relatively new persistent organic pollutants (POPs) because of their persistence, bioaccumulation, and potential toxicity. The aim of this work was to optimize the methods for the determination of selected synthetic fragrances in wastewater (municipal, industrial) and in fish muscle. These analytes were determined in wastewater [the wastewater treatment plant (WWTP) Brno – Modřice, cosmetic manufacturing plant] and in fish Squalius cephalus that had been caught in the river Svratka. The selected analytes (14 substances) originate from the group of nitromusk, polycyclic musk and linear musk compounds. Solid phase microextraction (SPME) [for wastewater samples] and pressurized solvent extraction (PSE) [for fish samples] were used for isolation of analytes from real samples. The identification and quantification of analytes were carried out by high resolution gas chromatography coupled with mass spectrometry detection (GC-MS). The results show that galaxolide (g.L-1) and tonalide (tenths of g.L-1) were polycyclic musk compounds which were found at the highest concentration level in influent and also in effluent samples from the WWTP Brno – Modřice. The most extended nitromusk compound was musk ketone (hundredths of g.L-1). Linear musk compounds were detected in all influent samples (g.L-1). The overall removal efficiency of synthetic musk compounds from wastewater in the WWTP varies within the following ranges: nitromusk compounds 34.4 % – 85.4 %, polycyclic musk compounds 36.7 % – 53.3 % and linear musk compounds 90.5 % – 99.9 %. On the basis of the results it can be stated that wastewater (effluent from the WWTP) is the primary source of musk compounds, especially of the polycyclic ones in the environment. It has been also shown that ultrafiltration used in a cosmetic plant is a highly efficient technology for removing nitromusk and polycyclic musk compounds from industry wastewater. The results from evaluation of the fish contamination by musk compounds show that galaxolide was the substance which reached the highest concentration levels (tens of g.kg-1 l.w.). The results corroborate ubiquitous occurrence of musk compounds in the environment and reduction of using of nitromusk compounds due to their potential toxic properties. It has been shown that the insufficiency of the purifying procedures used in the WWTP Brno – Modřice has a significant influence on the concentration level of polycyclic musk compounds (tonalide, galaxolide) in fish caught from the river Svratka.
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Possibilities of elimination of sulfonamides from the aquatic ecosystem
Suková, Petra ; Mravcová, Ludmila (referee) ; Vávrová, Milada (advisor)
This diploma thesis focuses on the determination of sulfonamide antibiotics especially the possibility of elimination of these substances from the aquatic ecosystem. Nowadays, environmental contamination of the pharmaceuticals and their residues is a serious concern. Main sources of this contamination are wastewater treatment plants (WWTPs), where these compounds are not effectively removed by contemporary conventional technology. For this reason, new methods are being developed and tested that could eliminate the number of contaminants entering the environment in this way. There is a possibility to use the potential of the enzymatic system of wood-decay fungi, especially white rot fungi. Six representatives of sulfonamide antibiotics were selected and isolated from the aquatic matrix via solid phase extraction. The final identification and quantification method was high performance liquid chromatography with mass spectrometric detection. Monitoring of the concentration level of selected sulfonamide antibiotics at the inflow and effluent at the Brno-Modřice WWTP was carried out weekly. Moreover, the effectiveness of elimination of selected antibiotics from the aquatic ecosystem by the use of Trametes versicolor wood-decay fungi cultured on a suitable carrier was verified.
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