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Removal of pharmaceutical products from water in wastewater treatment plants
Hamanová, Sabina ; Fuksa, Josef (advisor) ; Cajthaml, Tomáš (referee)
This thesis deals with removal of pharmaceuticals and personal care products by constructed wetlands (CWs) and compares its efficiency with removal efficiency of mechanical-biological conventional wastewater treatment plants (WWTP). In the first part the structure of WWTP is described, followed by the structure of CW. Special attention is also paid to the types of CWs, basic principles of function, physical-chemical parameters and vegetation. Below in literature review based on recent works is introduced characterization of selected pharmaceuticals with possible risks. The final section is focused on comparison of case studies from different countries in the world, oriented to the removal of organic polutants, especially PPCPs, from wastewater using various mechanisms including the use of constructed wetlands. Key words: PPCPs, constructed wetland, wastewater treatment plant, wastewater
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Removal of micropollutants from wastewater by adsorbtion.
Trávníček, Jakub ; Macsek, Tomáš (referee) ; Hlavínek, Petr (advisor)
The aim of the thesis is to create a research on the issue of adsorption of micropolutants with a subsequent focus on biochar. The first part therefore deals with the micropolutants themselves, the origin of their formation in wastewater and their negative impact on the health of organisms. It also deals with adsorption technology, discusses its basic knowledge necessary to grasp the topic and describes known adsorbents and their use. It pays special attention to biochar. The second part of the thesis deals with practical filter tests of adsorption abilities of biochar on wastewater from tunnel maintenance and treatment carried out in the laboratory of the AdMaS centre.
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Microbial community in sediments of a stream contaminated by pharmaceuticals
Brťková, Hana ; Cajthaml, Tomáš (advisor) ; Zikánová, Blanka (referee)
Pharmaceuticals are micropollutants, that enter the environment mainly through Wastewater Treatment Plants (WWTPs). In this work microbial community has been studied in sediments of a stream, which is located near a WWTP. This sediment is contaminated with pharmaceuticals. The subject of this thesis was to determine the presence of pharmaceuticals and microbial community in this study site and to point out possible relationships between these factors. Twelve pharmaceuticals were identified at concentrations reaching levels of ng/g. The concentrations of the compounds form a gradient that decreases with the distance from WWTP. Microbial biomass was estimated using the analysis of phospholipid fatty acids and microbial community was described using next-generation DNA sequencing. The analysis of phospholipid fatty acids pointed out, that with the increasing distance from WWTP the amount of microbial biomass decreases. DNA sequencing revealed large microbial diversity in the studied sediment. For evaluation of the relationship between the microbial community and pharmaceuticals in the stream sediment, Principal Component Analysis (PCA) was used. The result of PCA showed, that in the stream sediment (depth 10-30 cm), Betaproteobacteria negatively correlated with triclosan and Clostridia negatively...
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Study of degradation of micropolutants in water using advanced oxidation processes
Brož, Tomáš ; Repková, Martina (referee) ; Mravcová, Ludmila (advisor)
This bachelor thesis is focused on the study of pesticide degradation using various advanced oxidation processes. Finding an effective method to degrade these micropollutants is very important with their increasing consumption in the agricultural and other industries, because their adverse effects on non-target organisms and humans are also expected. In this work, the herbicides metazachlor and chloridazon were studied. The first part of this work is conceived theoretically and is focused on a basic description of advanced oxidation processes, including characterization of individual types, description of pesticides and their distribution and a brief description of the used analytical methods. The second part deals with the experiment itself and the evaluation of the results. Three different types of advanced oxidation processes were used for degradation: UV, H2O2, UV/ H2O2. Liquid chromatography with tandem mass spectrometry (LC/MS) was used to determine the efficiency of the experiment. It was found that the most effective of the used degradation methods was the use of UV radiation with the addition of H2O2.
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Composting of materials contaminated by micropollutants
Kočí, Petra ; Cajthaml, Tomáš (advisor) ; Innemanová, Petra (referee)
Micropollutants are compounds of anthropogenic origin, detected at concentrations of ng·g-1 - mg·g-1 in the environment. Micropollutants are synthetic or natural compounds. Micropollutants are released into the environment due to various human activities. Despite low concentrations in the environment, they represent a real threat to organisms, because of their specific biological effects. Sewage sludge is used in agriculture due to its hight nutritious content. Via using sludge in agriculture, contained micropollutants can be released to environment. Composting is a cheap bioremediation method, used from 80's of the last century. This diploma thesis is focused on composting of sewage sludge, contamined with micropollutants. High degradation rate was observed in artificially contaminated sludge, mainly with endocrine disruptors (up to 100 %). Lower degradation rate was observed in sewage sludge from a pharmaceutical plant, some of the compounds were not degraded at all.
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Effect of emergent micropolutants on the denitrification activity of activated sludge
Mosná, Silvia ; Stříteský, Luboš (referee) ; Hrich, Karel (advisor)
Diploma thesis Effect of emergent micropolutants on the denitrification process through activated sludge is focused on three specific substances. The substances under investigation are atrazine, terbutylazine and sulfametaxazole. Atrazine and terbutylazine are pesticides, particularly herbicides. Sulfametaxazole was chosen as a common antibiotic. The thesis is summarized into 10 chapters and conclusion. The work consists essentially of theoretical and practical part. Part of the theoretical part of the thesis is legislation that deals with the matters of the problem with micropolutants. The next chapter is an introduction to the issue, where we want to familiarize the reader with the current situation. There are also chapters on emergent micropolutants, denitrification and investigated substances. If we look at the practical part, there are chapters on sampling, evaluation of BATCH tests and evaluation of inhibition tests. There are also chapters on BATCH tests and respiratory inhibition test, which describe procedures of how we performed this test. Laboratory test reports are included in the Annex.
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Monitoring drug removal efficiency from water by selected adsorbents
Moravčíková, Světlana ; Talašová, Lucie (referee) ; Biela, Renata (advisor)
This diploma thesis deals with the efficiency of removal of pharmaceuticals from drinking water by selected adsorption materials. The first part describes sources of pharmaceuticals in drinking water and possible ways of contaminating water by pharmaceuticals. Subsequently, the pharmaceuticals most commonly found in the environment - nonsteroidal anti-inflammatory drugs, antibiotics, psychiatric drugs and sex hormones - are described in more detail. Next, the thesis describes the processes used for removal of pharmaceuticals. These are activated carbon adsorption, membrane processes and advanced oxidation processes. The last chapter of the theoretical part of the thesis deals with water treatment plants, where the technologies for removing drugs are already in operation. In the practical part of this thesis an experiment was performed and evaluated, for a purpose of comparing the efficiency of selected sorption materials in the removal of diclofenac from water. Filtrasorb F100, Bayoxide E33 and GEH were used.
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Removal of pharmaceutical products from water in wastewater treatment plants
Hamanová, Sabina ; Fuksa, Josef (advisor) ; Cajthaml, Tomáš (referee)
This thesis deals with removal of pharmaceuticals and personal care products by constructed wetlands (CWs) and compares its efficiency with removal efficiency of mechanical-biological conventional wastewater treatment plants (WWTP). In the first part the structure of WWTP is described, followed by the structure of CW. Special attention is also paid to the types of CWs, basic principles of function, physical-chemical parameters and vegetation. Below in literature review based on recent works is introduced characterization of selected pharmaceuticals with possible risks. The final section is focused on comparison of case studies from different countries in the world, oriented to the removal of organic polutants, especially PPCPs, from wastewater using various mechanisms including the use of constructed wetlands. Key words: PPCPs, constructed wetland, wastewater treatment plant, wastewater
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Options removal of micropollutants with water treatment processes
Zdražilová, Alena ; Bogáňová, Ida (referee) ; Biela, Renata (advisor)
This diploma thesis is engaged in problems of micropollutants removal by water treatment process. The first part aims to define single micropollutants, possibilities of their removal in laboratory and micropollutants removal on water treatment plant. In the second part, there is data evaluation of water analyses on factual water treatment plant. Also there is description and evaluation of experiment, which aims to pesticide removal from river by using filtration across granulated active carbon.
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Use of oxidation processes (AOP) for removal of micropolutants
Stříteský, Luboš ; Pešoutová,, Radka (referee) ; Hlavínek, Petr (advisor)
This thesis deals with advanced oxidation processes (AOPs) and it’s use for removal of micropollutants from wastewater. The first chapter explains the need AOPs, water quality, pollution and substances that are present in the water. Further, the first chapter outlines approach of the current legislation to micropollutants. The second chapter explains the theory and principle of operation of AOPs. This chapter is divided into two sections. The first section describes AOPs, which were tested at selected WWTP. In the second section, there are described some other AOPs. The third chapter is a literature retrieval of AOPs dealing with the removal of micropollutants. This chapter is focused on the removal of hormones by AOPs using ozone-based AOPs. The fourth chapter describes the actual testing of selected AOPs. The chapter describes selected WWTP, pilot-scale AOP unit and test results. In the last chapter there is designed and described full-scale AOP tertiary unit for removing of micropollutants. The last chapter also contains economic analysis of the proposed tertiary unit.
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