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Evaluation of properties of clear and pigmented asphalt binders
Kamanová, Monika ; Machalla, Michael (referee) ; Dašek, Ondřej (advisor)
The Bachelor thesis subject is comparison of the chosen parameters of clear asphalt binder with pigmented asphalt binder. The theoretical part explains parameters of asphalt binders and improving their properties after using additives. The second part is explaining methods and test results. The empirical tests (needle penetration, softening point, breaking point) and performance tests in dynamic shear rheometer and bending beam rheometer are used for comparison of binders properties. In the conclusion the laboratory aging of asphalt binders is described by RTFOT and RTFOT + PAV method.
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Modification of Organic High Performance Pigments for Applications in Organic Electronics
Cigánek, Martin ; Imramovský, Aleš (referee) ; Vyňuchal, Jan (referee) ; Krajčovič, Jozef (advisor)
Dizertační práce pojednává o studiu, syntéze a chemické derivatizaci molekul spadajících do skupiny organických vysoce výkonných pigmentů a jejich potenciálním uplatnění v oblastech organické elektroniky. Teoretická část práce je zaměřena na nejnovější trendy v dané oblasti, a to jak z aplikačního potenciálu konkrétních derivátů, tak z pohledu syntetických možností a jejich strukturálních derivatizací. V experimentální části je pak podrobně popsána příprava pestré škály intermediátů a výsledných produktů, zahrnujících deriváty diketopyrrolopyrrolů (DPP), benzodifuranonu (BDF), epindolidionu (EP), naphthyridinedionu (NTD) a polymeru na bázi thiofenu (PT). Celkově bylo nasyntetizováno 103 molekul, přičemž 49 tvořily výsledné produkty, z nichž 27 bylo zcela nových, dosud nepublikovaných. Hlavním motivem derivatizace molekul pigmentů je zde inkorporace derivátů adamantanu do finálních struktur. V další části práce jsou blíže diskutovány jednotlivé chemické modifikace vedoucí k výsledným produktům. Na sérii N,N'-; N,O'- a O,O'-substituovaných derivátů DPP je popsána komplexní studie vlivu charakteru alkylových řetězců a také pozice jejich navázání v molekule DPP, a to nejen na selektivitu reakce, ale rovněž na optické i termické vlastnosti syntetizovaných produktů.
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Study of particles of various cosmetic pigments
Cerevatova, Kristina ; Opravil, Tomáš (referee) ; Zemanová, Jana (advisor)
The main focus areas of this master thesis include the writing of a literature review, which contains an overview and segregation of pigments which are used in the preparation of cosmetic products. The thesis is focused on the properties and characterization of pigments for use in cosmetology. The following focus is on legislation, more specifically on pigments that the cosmetic industry allows, limits and does not allow. The main part of this thesis is an overview of methods for the characterization of pigments. The practical part deals with the characterization of particles of selected cosmetic pigments by applying methods for determination of color, elemental and phase composition, particle size and morphology. The thesis is concluded by evaluation of the achieved results.
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Isolation, characterization and application of biomedically important polymer P(3HB-co-4HB)
Krupičková, Kristýna ; Přikryl, Radek (referee) ; Obruča, Stanislav (advisor)
This diploma thesis deals with the isolation and characterization of copolymer P(3HB-co-4HB). The teoretical part was prepared as a literature search which describe polyhydroxyalkanoates in general, their structure, synthesis, degradation and isolation. Furthermore, copolymers containing 4HB units are mentioned in this thesis and there is also no mentioned of the biosynthesis and biodegradation of copolymer P(3HB-co-4HB). The first aim of this diploma thesis was to find out which solvent is the best for copolymer extraction and then characterize obtained copolymer P(3HB-co-4HB). The isolated copolymer was characterized by gas chromatography, SEC-MALS, thermal analysis and SEM. In the second part of the thesis, release of model biologically active substance from the PHA films was studied. Rhodamine 6G dye was selected for the simulation, which was used to stain the copolymer films and the P(3HB) films. It was observed that film prepared from P(3HB-co-4HB) copolymer released entrapped substance much faster than film made from P3HB homopolymer, and, in addition, the copolymer was substantially more susceptible to enzyme degradation.
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Color Changing of the Ceramic brick.
Kocmánek, Tomáš ; Zach, Jiří (referee) ; Nevřivová, Lenka (advisor)
The bachelor’s thesis is focused on color correction of brick body. There are examples of pigments commonly used in various industrial fields, as well as studies on the use of waste products as additives in brickmaking industry, altering, among other things, the color of the brick body. In the experimental part of the thesis the effect of three selected ferric pigments and two selected correction clays on the color and selected physico-mechanical properties of the brick body was investigated.
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Influence of input materials for quality architectural concrete
Ondryášová, Veronika ; Novosad, Petr (referee) ; Hela, Rudolf (advisor)
This diploma thesis focuses on the influence of properties of feedstocks for the production of quality surfaces of architectural concrete. The introductory part describes the definition of architectural concrete with the advantages and disadvantages of its implementation. In the following chapters, the characteristics, the dosage or the chemical composition of the input materials are given. Besides the design of the mixture, important parameters for the creation of a quality surface of concrete are compaction, precise placement in formwork and subsequent treatment of the surface. Individual types of architectural concrete, their method of production with the examples belonging to concrete constructions are also given. In the practical part, 4 mixtures were designed, whose type or dosage of feedstocks was changed. In creating mixtures, emphasis was placed on minimal segregation of fresh concrete and the formation of pores on the surface of hardened concrete.
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Studium sekvencí genů zbarvení u činčil na základě homologie se sekvencemi vybraných savců
Poslušná, Michala
In domesticated animals there are many different coat colours and mutations, often connected with pleiotropic effects. The aim of this thesis named The study of colour genes sequences in chinchilla based on homology of human and mice sequences was describe molecular genetic principles of pigmentation, introduce genes involved in melanogenesis and influencing a melanin function, their structure, mutations and mention other mutations which change the phenotype. Informations about alleles TYR, TYRP1, TYRP2/DCT, agouti, AGRP, gene group MCR (MC1R-MC5R) and more are focused on human (Homo sapiens), mouse (Mus musculus) and chinchilla (Chinchilla lanigera). In these three species was compared selected genes sequences TYR and TYRP2/DCT, results were studied, commented and mutations, which are very specific, but there are some analogs between human and mouse, were highlighted.
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Architectural concrete
Novosad, Petr ; Ďurica,, Tibor (referee) ; Dulenčín, Juraj (referee) ; Klečka,, Tomáš (referee) ; Hela, Rudolf (advisor)
In the development of concrete structures and its finishes we are constantly looking for new ways to highlight the aesthetic value of the concrete. With all the possibilities of shapes, textures and colours, an architectural concrete in the hands of an architect and designer becomes a material, which can be used to express different individual and specific ideas. It is necessary to recognize and cope with these possibilities, but also the limits, which determine the properties of concrete as the proper design and implementation creates excellent finishes that are otherwise inaccessible to other materials and technologies. The theoretical part includes an extensive summary carries out a research on issues of architectural concrete and its production. From this research comes a new definition of architectural concrete and the newly redesigned and determined classes of architectural concrete with respect to the continuous development of technologies and production possibilities, rendering and surfacing. The aim of the thesis is to verify the possibilities of producing quality architectural concrete and additional treatment of the surface with respect to the desired aesthetic quality.
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