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Sensoric Properties of Organic Materials
Tmejová, Kateřina ; Zmeškal, Oldřich (referee) ; Kratochvílová, Irena (referee) ; Nešpůrek, Stanislav (advisor)
The first part of the work is aimed to the study of changes of electrical properties of substituted phthalocyanines under the influence of humidity. Thin films were prepared by spin coating technique. During the influenece of humidity electrical conductivity increases. Sorption and desorption and the changes in electrical properties under the repated humidity exposure were investigated as well. Impedance spectroscopy was used for the studies. The second part of this work consists of optical studies and changes of optical parametrsunder the influence of different alcohols (methanol, ethanol, 2-propanol) exposures. The investigated samples were prepared by vacuum evaporation a glow-discharge-induced sublimation. The changes of optical reflectances of the films upon exposure to alcoholvapour-containg atmospheres were studied as a function of alcohol concetration and exposure time.
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Organic solar cells based on lowmolecular materials
Omasta, Lukáš ; David, Jan (referee) ; Weiter, Martin (advisor)
This bachelor thesis is focused on characterization of new organic materials suitable for use in solar cells. In the theoretical part, there is research on organic solar cells together with description of the photovoltaic energy conversion. In this part, description of the structure and general properties of materials used to produce solar cells is given. The individual characterization methods are also described. The practical part includes the preparation of thin layers of organic materials and their optical characterization. Preparation of solar cells with classic structure is also included together with evaluation and comparison of their photoconductivity and efficiency.
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Deposition and characterization of low molecular thin films for organic photonics
Omasta, Lukáš ; Salyk, Ota (referee) ; Weiter, Martin (advisor)
This diploma thesis is focused on characterization of properties of new organic materials with respect to its potential application in organic photonics. The theoretical part contains a themed literature research on low molecular thin films for organic photonics, mainly phthalocyanines together with description and structure of the photovoltaic energy conversion. The practical part includes the preparation of thin layers of selected organic materials for organic photonics. Prepared thin films were characterized by optical methods and current voltage characteristics. Based on these results, the thin films and structure of solar cells were optimalized. Acquired data were used to determine the materials and structures suitable for photonics applications.
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Study of optoelectrical properties of organic semiconductor thin film layers of phtalocyanines
Miklíková, Zdeňka ; Vala, Martin (referee) ; Zmeškal, Oldřich (advisor)
Diploma thesis is focused on the study of optoelectric properties of thin layers of organic materials based on phthalocyanines, which can be used as an active layer of photovoltaic cells. Especially are studied the properties of the thin active layers of PdPc and PdPc + IL on the glass or ceramic substrates with aluminium contact, which are prepared by material printing here. On the prepared samples were first measured current-voltage characteristics in the dark and in the light and then were measured impedance spectrums in the dark. The received results will be used to improve the properties and structures of photovoltaic cells.
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Cobalt phthalocyanines as sensors for detection of htiol groups
Vaňková, Kateřina ; Nesměrák, Karel (advisor) ; Schwarzová, Karolina (referee)
Title: Cobalt phthalocyanines as sensors for determination of thiol groups Annotation: The possibility of employment of cobalt phthalocyanine as a material for the modification of HOPG electrode for construction of a sensor for quantification of thiol groups was studied. Thiol groups are occurring in various biologically active substances (sulfur amino acids). The electrochemical behavior of cobalt tetraneopentoxy-phthalocyanine (CoTNPc) in the water/organic phase system was studied, and individual peaks of cyclic voltammogram of the compound were identified. The electrodeposition of CoTNPc on HOPG electrode was found as a suitable method for construction of the sensor for quantification of thiol groups. The reproducibility of fabrication of the sensor and its time-stability was studied. The calibration dependencies for model analytes (cysteine hydrochloride and homocysteine) were measured. Key words: thiols, phthalocyanines, amperometric sensor, cyclic voltammetry
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Preparation of the Si(110)-Tl surface for deposition of organic molecules
Slezák, Peter ; Kocán, Pavel (advisor) ; Zimmermann, Petr (referee)
This bachelor thesis deals with the formation of an anisotropic surface Si (110) -Tl, which will serve as a substrate for the deposition of organic molecules of copper phthalocyanines. The aim was to identify relevant preparation parameters and optimize the producting process of surface Si (110) with the reconstruction (16x2), to find the best parameters for deposition of thallium on this surface so as to produce a surface Si (110) -Tl with reconstruction (1x1) and test the suitability of this surface as a substrate for further deposition of organic molecules. In the course of the work, the apparatus used for measurements is described, the individual measurement procedures and the physical principles associated with STM operation are also described.
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Preparation of the Si(110)-Tl surface for deposition of organic molecules
Slezák, Peter ; Kocán, Pavel (advisor) ; Zimmermann, Petr (referee)
This bachelor thesis deals with the formation of an anisotropic surface Si (110) -Tl, which will serve as a substrate for the deposition of organic molecules of copper phthalocyanines. The aim was to identify relevant preparation parameters and optimize the producting process of surface Si (110) with the reconstruction (16x2), to find the best parameters for deposition of thallium on this surface so as to produce a surface Si (110) -Tl with reconstruction (1x1) and test the suitability of this surface as a substrate for further deposition of organic molecules. In the course of the work, the apparatus used for measurements is described, the individual measurement procedures and the physical principles associated with STM operation are also described.
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Cobalt phthalocyanines as sensors for detection of htiol groups
Vaňková, Kateřina ; Nesměrák, Karel (advisor) ; Schwarzová, Karolina (referee)
Title: Cobalt phthalocyanines as sensors for determination of thiol groups Annotation: The possibility of employment of cobalt phthalocyanine as a material for the modification of HOPG electrode for construction of a sensor for quantification of thiol groups was studied. Thiol groups are occurring in various biologically active substances (sulfur amino acids). The electrochemical behavior of cobalt tetraneopentoxy-phthalocyanine (CoTNPc) in the water/organic phase system was studied, and individual peaks of cyclic voltammogram of the compound were identified. The electrodeposition of CoTNPc on HOPG electrode was found as a suitable method for construction of the sensor for quantification of thiol groups. The reproducibility of fabrication of the sensor and its time-stability was studied. The calibration dependencies for model analytes (cysteine hydrochloride and homocysteine) were measured. Key words: thiols, phthalocyanines, amperometric sensor, cyclic voltammetry
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Sensoric Properties of Organic Materials
Tmejová, Kateřina ; Zmeškal, Oldřich (referee) ; Kratochvílová, Irena (referee) ; Nešpůrek, Stanislav (advisor)
The first part of the work is aimed to the study of changes of electrical properties of substituted phthalocyanines under the influence of humidity. Thin films were prepared by spin coating technique. During the influenece of humidity electrical conductivity increases. Sorption and desorption and the changes in electrical properties under the repated humidity exposure were investigated as well. Impedance spectroscopy was used for the studies. The second part of this work consists of optical studies and changes of optical parametrsunder the influence of different alcohols (methanol, ethanol, 2-propanol) exposures. The investigated samples were prepared by vacuum evaporation a glow-discharge-induced sublimation. The changes of optical reflectances of the films upon exposure to alcoholvapour-containg atmospheres were studied as a function of alcohol concetration and exposure time.
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Study of optoelectrical properties of organic semiconductor thin film layers of phtalocyanines
Miklíková, Zdeňka ; Vala, Martin (referee) ; Zmeškal, Oldřich (advisor)
Diploma thesis is focused on the study of optoelectric properties of thin layers of organic materials based on phthalocyanines, which can be used as an active layer of photovoltaic cells. Especially are studied the properties of the thin active layers of PdPc and PdPc + IL on the glass or ceramic substrates with aluminium contact, which are prepared by material printing here. On the prepared samples were first measured current-voltage characteristics in the dark and in the light and then were measured impedance spectrums in the dark. The received results will be used to improve the properties and structures of photovoltaic cells.
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