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The family house in Dubčany
Nedozrál, Milan ; Podivinský, Jaroslav (referee) ; Krupicová, Jana (advisor)
This thesis focuses on the family house design and preparation of its project anglickém jazyce documentation. The house is standing on a building estate number 106/23 in the cadastral area Dubčany u Choliny (652342). The layout of the house has the shape of letter T with the dimensions of 14.85 x 11.6 m. It is a two storey building with one ground floor and the attic. On the first floor there is a vestibule, hall, toilet, kitchen, pantry, living room with dining room, study, utility room and garage. In the attic there is a hallway, bedroom, dressing room, three bedrooms and two bathrooms. The house is based on concrete strips. The vertical and horizontal structures are from system HELUZ. The roof of the house is a gabled, with a slope of 40 °, plotted wooden rafters.
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Design of steel-concrete composite structure of road bridge in Trenčín
Doležal, Tomáš ; Marván, David (referee) ; Nečesal, Petr (advisor)
The aim of diploma thesis was to design alternative of composite road bridge in Trenčín. The bridge beam is designed as continuous with theoretical span of 65 m + 106 m + 65 m. Permanent load, climatic load (uniform and nonuniform temperature variation, windload), shrinkage, differential settlement and traffic load were taken into consideration according to Eurocodes. Technical report, static report, drawings, bill of quantities are included. Computational model for evaluation of internal forces was carried out in SCIA Engineer software.
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Residential Complex in Brno - Komín
Jánsky, Matúš ; Štěrbák, Edvard (referee) ; Novák, Antonín (advisor)
The goal of the project was to design a housing structure on a site located in district Komín in Brno. The residential complex for parrents with young children is designed as a three to four storey mass with a core in form of an open block. The modern architecture of the complex is characterized by wood cladding on the facade and large format of windows. The complex is follows the sloping of the terrain
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Nickel alloy overlay welding parameters optimalization
Lauš, Lukáš ; Kubíček, Jaroslav (referee) ; Sigmund, Marian (advisor)
The aim of these master's thesis is to choose and optimize parameters of the Venturi tube throat weld cladding. The Venturi tube is made from carbon steel ASME SA-106 Grade C. The weld cladding is performed by plasma transferred arc welding. The throat is weld overlaid with nickel base powder Inconel 625. The overlays are made without oscilation. The main requirement was to find a maximum possible powder feed rate and others welding parameters to develop maximum welding speed and productivity on automat. Visual and penetrant testing on the overlays were performed. Metalographic samples were prepared. On the samples was meassured dilution, overlay thickness and width of the heat affected zone. Results are compared with parameters succesfully used in the cooperating company.
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Fast charger for the traction accumulator of the electric vehicle "Peugeot 106 electric"
Langer, Radim ; Huták, Petr (referee) ; Vorel, Pavel (advisor)
This diploma thesis refers to Terminal project 1 and Terminal project 2 from former years of my studies. This work engages in design and construction of high-current charger for the electric vehicle Peugeot 106. Firstly, there is given an account of electric vehicle. There is made reference to its parameters and the way of its battery charging part. Secondly, the work deals with design concept of high-current charger and with its theoretical lay-out. Respectively, this work substantially touches on issues of chosen power, control, regulative and protective circuits of high-current charger. Thirdly, practical assembly procedure of high-current charger is detailed. Dimensioning of particular elements is described in this work. Photos and schemes of given apparatus are shown. Last but not least, results of measurement on assembled high-current charger are stated in this work.
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Influence of electrolysis on the degradation of dye water solutions
Olexová, Barbora ; Možíšková, Petra (referee) ; Kozáková, Zdenka (advisor)
The basic subject of this thesis is to investigate the influence of electrolysis on degradation of organic dyes in aqueous solutions. Electrolysis is a physically-chemical process, during which - under the influence of direct current - chemical reactions proceed inside the system. By choosing efficient conditions it is possible to achieve fundamental changes in the structure of organic compound’s molecules and on the basis of that for example their gradual degradation. This effect can be used in the process of wastewater treatment. The main task of the thesis is to analyse the influence of variously chosen chemical and physical conditions on the rate of degradation of azo dyes, which is the largest group of organic dyes used in industry and from this reason in great amounts contained both in mill residues and sewage water. Azo dyes have been selected for this experiment for their good solubility in water. Other advantage is that their degradation is accompanied by visible decoloration of the solution and their concentration in solution can be easily determined by UV-VIS spectrometry. Concretely two direct azo dyes - C.I. Direct Blue 106 and C.I. Direct Red 79 - have been chosen. The experiment was carried out in a simple reactor consisted of a bath with a stirrer into which two electrodes were installed and attached to the source of direct voltage. Every series of measurement proceeded at constant current which values were varied in range from 100 mA to 1 000 mA. The electric voltage ranged from 7 V to 22 V. Several samples were taken away from the solution during the experiment and the decrease of dye concentration was evaluated in every series. This evaluation validated the hypothesis that the dyes contained in the solution really degraded. This process was also connected to the expected bleaching of the solution. Decoloration of aqueous solution of dye is caused by disruptions in the structure of the dye molecule which is loosing its characteristic sections that cause colourfulness (a conjugate system of double bonds and presence of appropriate substitutes). A total amount of measured series was 16 with various input conditions (Fe and Pt electrodes, electrolytes NaCl, Na2SO4, and NaNO3 and their different concentrations, different current values) which more or less influenced the rate of degradation of investigated substances. It was found out that the blue dye is more likely to be electrolytically degraded. Chemical structure of its molecules, which is smaller and less branched than molecules of the used red dye, could be the source of that. The greatest degradation of the blue one proceeded at two chosen maximum values of constant current 800 mA and 1 000 mA. It could be assumed that current enhancement through the system induces higher dye concentration decrease. Degradation of the blue dye proceeded faster by using electrodes made of stainless steel than the platinum electrodes. The most suitable electrolyte was shown to be sodium chloride. When higher concentration (or conductivity) of electrolyte was used higher efficiency of degradation process was observed.
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Aroma active compounds of selected types of herbs
Škutová, Pavla ; Hrstka, Miroslav (referee) ; Vítová, Eva (advisor)
This diploma thesis deals with the identification of aroma active compounds in medicinal herbs. The group consists of 5 types of herbs: lemon balm (Melissa officinalis), pot marigold (Calendula officinalis), clary sage (Salvia sclarea), milk thistle (Silybum marianum), goat’s rue (Galega officinalis). These plants are known for their positive effects in folk medicine. The SPME-GC-MS method was chosen to characterize the fragrances. During the identification of volatile compounds, emphasis was put on suspected fragrance allergens listed in EC Regulation 1223/2009 in Annex III. Overall 106 compounds were identified together with 8 allergens in lemon balm, pot marigold contained 104 compounds with 7 allergens included, 82 compounds including 5 allergens in clary sage, 73 compounds were identified in milk thistle including 6 allergens and 110 compounds with 9 allergens included in goat’s rue.
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Bridge over a local road and brook
Večeřa, Jan ; Pachl, Radek (referee) ; Panáček, Josef (advisor)
The Diploma thesis deals with the design of the bridge construction that conveys the road I/11 across the Bystry brook and the local road between Nebory and Oldřichovice. The construction is designed in four options, one of which was selected is the variation of the prestressed onebeam construction of four fields and the lenght of bridging 106,6 m. Calculation of the effects of the load is carried by a computer program Scia Engineer. Assessing the design is done in accordance with applicable European standards EN 1992-1-1. It is also elaborated well arranged drawing documentation, construction process and visualization of the bridge.
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Study of influence of organic dye structure on their decomposition in the diaphragm discharge in liquids
Pajurková, Jana ; Fasurová, Naděžda (referee) ; Kozáková, Zdenka (advisor)
The main goal of presented thesis is to study the influence of organic dyes structure on its degradation in diaphragm discharge in liquids. Diaphragm discharge is a kind of non-thermal plasma that can be generated in liquids by the application of high voltage. In plasma channels (so-called streamers), many physical and chemical processes are formed. High electrical field, shock waves and last but not least emission of electromagnetic waves in the range of visible and ultra-violet radiation appear among physical processes. The most important chemical process is generation of active species. These species initiate chemical reactions and could attack molecules of organic compounds contained in water solution. The reason why organic dyes were chosen in this study is its visible destruction, because it is related to its decolouration. Further, UV-VIS spectroscopy for the determination of concentration during the experiment can be used. Organic dyes are good models of organic substance often contained in waste water and for which removal classical biological, chemical and physical methods aren’t sufficient. Selected dyes were mostly from the group of azo-dyes: Acid Red 14, Acid Red 18, Acid Yellow 23, Direct Blue 53, Direct Red 79, Direct Red 80, Direct Yellow 29, Food Yellow 3 and further, Acid Blue 74 (indigotic dye) and Direct Blue 106 (oxazine dye). Experiments were carried out in a special batch discharge reactor with the anode and the cathode spaces divided by a non-conductive barrier, where the diaphragm with a pin-hole was placed. Measurement showed different removal in the anode and cathode space. We have supposed it was caused by different streamers features and energetic conditions. Dyes were decomposed with higher efficiency in the anode space where the final concentration reached 40 % of the initial concentration while it remained about 90 % in the cathode space. In this thesis the influence of dyes structure on the dye decomposition by electrical discharge was investigated. Dyes consisted of small molecules and dyes with many substitutes bounded on aromatic ring were decomposed more easily than dyes consisted of big molecules. The shift of characteristic wavelength on both directions (to shorter as well as longer wavelength) was observed during the experiments especially when the Direct dyes were decomposed. This phenomenon was probably due to the formation of intermediate product, which have different characteristic wavelength than the primary compound. In general, colourfulness is given by long conjugated systems of double bonds with substitutes bounded on an aromatic ring. Each change in the molecule structure provides the colour change and this could be the possible reason of the shift of characteristic wavelength. The other task was the comparison of degradation process efficiency by the mean of electrolysis and diaphragm discharge. Results showed that electrolysis (30 W) was more convenient for degradation of dyes consisted of small molecules while diaphragm discharge (130170 W) suited for complex molecules. For degradation of small molecules, oxidation on the anode assumed to be the most effective process that is initiated by electrolysis. For degradation of big molecules, attack of active species produced by the discharge is necessary.
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Study of electrolytic influence on organic dye decomposition in the diaphragm discharge in liquids
Davidová, Jaroslava ; Rašková, Zuzana (referee) ; Kozáková, Zdenka (advisor)
This Bachelor thesis is focused on study of chemical and physical influences which are proceed in diaphragm discharge in water solution. These processes could be used in water treatment. If DC non-pulsed voltage is applied, a significant influence of electrolysis must be taken into account. The main goal of this thesis is the estimation of electrolytic contribution to processes in the discharge. Theoretical part describes basic theory about creation of electrical discharges in water and electrolysis with emphasis on processes leading to destruction of organic compounds. Production of reactive particles (radicals, hydrogen peroxide, ozone, etc.) and electrochemical reactions on electrodes mainly belongs among these processes. This part describes analytical method (UV-VIS spectroscopy) which was used for determination of organic dyes concentration as well. Experimental part is oriented to experiment procedure which was carried out in an apparatus with separated anode and cathode area. Separation was made by dielectric diaphragm with a pinhole in the centre. Its initial diameter was 0.25 mm. Electrolytic decomposition was carried out at constant current of 30 mA and supplied power was about 14–32 W. Two Saturn dyes (Direct Blue 106 and Direct Red 79) were selected for experiments. As the decomposition was related to decoloration of the solution, UV-VIS spectroscopy in the range of 350–700 nm was used for determination of dye concentration. Next part focused on results presents various factors which had remarkable effect on decomposition of organic dyes. These factors were: various polarities of electrodes, conductivity and pH of solution, applied power, kind of electrolyte and structure of organic dye. The electrolysis had the significant influence on decomposition of small organic molecules. Decomposition was running mainly in the anode area where so called negative discharge was created. Optimal conditions were set by NaCl electrolyte with concentration providing initial conductivity of 500 S·cm-1. By the NaNO3 electrolyte half decomposition efficiency was achieved and in Na3PO4 electrolyte, the decomposition even didn’t run. The decomposition in the anode area was stimulated by the low pH value, which was decreasing during electrolysis. Generally, higher decomposition was achieved by the discharge than by pure electrolysis but the electrolysis had higher efficiency. In pure electrolysis, high rate of removal can be achieved by the application of a relatively low power. When bigger organic molecules were decomposed, the efficiency was higher by applying the discharge.
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