Národní úložiště šedé literatury Nalezeno 3 záznamů.  Hledání trvalo 0.00 vteřin. 
Electrochemical and spectroelectrochemical study of nanocrystalline TiO2 anatase with exposed (001) faces
Lásková, Barbora ; Zukalová, Markéta ; Bouša, Milan ; Kavan, Ladislav ; Liska, P. ; Grätzel, M.
The electrochemical and spectroelectrochemical behavior ot TiO2 anatase with a predominant (001) face was studied and compared to a reference anatase material with dominating (101) face. The electrochemical measurements indicate that Li-ion insertion/extraction is facilitated for TiO2 anatase with (001) faces as compared to (101) one. The performance of both different crystal morphologies as a photoanode material in DSC (dye sensitized solar cell) was tested too. The (001) face adsorbed smaller amount of the used dye sensitizer (C101) but provides larger open circuit voltage (Uoc) of the solar cell. The different band energetics of both particular morphologies was suggested to be the reason for the voltage enhancement of the device employing (001) anatase. To prove our hypothesis and determine their flatband potential, a spectroelectrochemical study of transparent films of nanocrystalline (001) and (101) anatase on coaducting glass was carried out. UV/Vis spectra were measured at potentials between 0 and -1.4V vs SCE and confirmed the negative shift of flatband potential for (001) anatase as compared to (101) one.
Nanocrystalline TiO2 anatase with a large proportion of crystal facets (001): electrochemical properties and performance in dye sensitized solar cell
Zukalová, Markéta ; Lásková, Barbora ; Kavan, Ladislav ; Chou, A. ; Liska, P. ; Wei, Z. ; Bin, L. ; Grätzel, M.
The theme od this work is nanocrystalline TiO2 anatase with a large proportion of crystal facets (001): electrochemical properties and performance in dye sensitized solar cell.

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