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Uehara cycle
Soška, Michal ; Škorpík, Jiří (referee) ; Fiedler, Jan (advisor)
This Diploma thesis describes design of the computational model of Uehara power cycle, with ammonia-water mixture used as working fluid. First part is dedicated to issue of determination working mixture thermodynamic properties, which are essential for computational model design. The second part of this thesis describes the methodology of computing power cycle by system matrix solving method. For purposes of methodology testing, model of Kalina power cycle was also created. Computational models of Uehara and Kalina cycles are designed in Excel and are an integral part of this thesis. Text part also includes a description of their user interface, calculation algorithm and detailed description of the design methodology.
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Arsenic speciation in mining wastes - case studies in systems dominated by ferric sulfoarsenates
Jelenová, Helena ; Drahota, Petr (advisor) ; Filippi, Michal (referee) ; Jurkovič, Ľubomír (referee)
The aim of the thesis is to study behavior and mineralogy of arsenic in mine wastes with high levels of FeIII and SVI . Three methodological studies are related to (i) identification and characterization of secondary arsenic phases using a Raman spectrometry, (ii) chemical fractionation of arsenic in mine waste materials as observed by optimized sequential extraction, (ii) and investigation of thermodynamic properties of zýkaite. The mineralogy and mobility of arsenic was studied in mine waste material of five dumps located at three sites (Kaňk near Kutná Hora, Jedová jáma near Vejprty, and Dlouhá Ves) and in stalactite samples from two abandoned underground mines (Plavno and Mikulov near Teplice). Mineralogical and geochemical characterization of samples included standard methods and techniques. Chemical composition of solid and liquid (pore water, leachates) samples was performed using a XRF, ICP OES, ICP MS, etc. X-ray diffraction, Raman spectrometry and electron microscope equipped with microanalysis were the most frequent techniques used for mineralogical characterization of the solids. The results showed that the speciation of arsenic in the solid phase significantly varied among the studied sites and was a function of total concentration as well as proportion of the major components of...
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Characterization of poly(1,4-diethynylbenzene) by IGC method
Petrášová, Sabina ; Sedláček, Jan (advisor) ; Pacáková, Věra (referee)
Poly(1,4-diethynylbenzene) ( -conjugated polymer) was prepared as an insoluble polymer network via chain coordination polymerization of 1,4-diethynylbezene catalyzed with [Rh(NBD)acac] complex. Thermodynamic properties and acid-base characteristics of the prepared poly(1,4-diethynylbenzene) were studied by means of Inverse Gas Chromatography (IGC) in the temperature range 80-100 řC. Retention data of selected testing substances were used to determine the Gibbs energy of sorption, the sorption enthalpy and their acid-base and disperse parts as well as the disperse contribution to the surface energy and parameters of KA, KD, ANHPS and DNHPS quantifying the acid-base character of the studied polymer. The results showed that poly(1,4-diethynylbenzene) interacted more efficiently with Lewis bases than with Lewis acids. The values of experimental sorption enthalpy were used for the determination of the parameters KA and KD. Values of these parameters classify poly(1,4-diethynylbenzene) as the material with a slightly acid character. This conclusion is further supported by the results of H. P. Schreiber method based on the application of ANHPS and DNHPS parameters for the evaluation of the acid-base properties of the material. The infrared spectroscopy proved that poly(1,4-diethynylbenzene) contained...
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Characterization of poly(1,4-diethynylbenzene) by IGC method
Petrášová, Sabina ; Sedláček, Jan (advisor) ; Pacáková, Věra (referee)
Poly(1,4-diethynylbenzene) ( -conjugated polymer) was prepared as an insoluble polymer network via chain coordination polymerization of 1,4-diethynylbezene catalyzed with [Rh(NBD)acac] complex. Thermodynamic properties and acid-base characteristics of the prepared poly(1,4-diethynylbenzene) were studied by means of Inverse Gas Chromatography (IGC) in the temperature range 80-100 řC. Retention data of selected testing substances were used to determine the Gibbs energy of sorption, the sorption enthalpy and their acid-base and disperse parts as well as the disperse contribution to the surface energy and parameters of KA, KD, ANHPS and DNHPS quantifying the acid-base character of the studied polymer. The results showed that poly(1,4-diethynylbenzene) interacted more efficiently with Lewis bases than with Lewis acids. The values of experimental sorption enthalpy were used for the determination of the parameters KA and KD. Values of these parameters classify poly(1,4-diethynylbenzene) as the material with a slightly acid character. This conclusion is further supported by the results of H. P. Schreiber method based on the application of ANHPS and DNHPS parameters for the evaluation of the acid-base properties of the material. The infrared spectroscopy proved that poly(1,4-diethynylbenzene) contained...
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Uehara cycle
Soška, Michal ; Škorpík, Jiří (referee) ; Fiedler, Jan (advisor)
This Diploma thesis describes design of the computational model of Uehara power cycle, with ammonia-water mixture used as working fluid. First part is dedicated to issue of determination working mixture thermodynamic properties, which are essential for computational model design. The second part of this thesis describes the methodology of computing power cycle by system matrix solving method. For purposes of methodology testing, model of Kalina power cycle was also created. Computational models of Uehara and Kalina cycles are designed in Excel and are an integral part of this thesis. Text part also includes a description of their user interface, calculation algorithm and detailed description of the design methodology.
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Thermodynamic and transport properties of ordinary water substance
Mareš, R. ; Šifner, Oldřich ; Královec, J.
A brief review of the internatonal temperature scales and its mutual conversion aids are presented. Shortly is discussed the development of new standards for the transport properties.The introduction of the new internationally adopted industrial formulation IAPWS-IF97 in the nuclear engineering practice is emphasised. Available sources of the formulation are given. Mentioned are new backward equations and TTSE method. The state in the field of the thermophysical properties of heavy water is summarized.
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