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Structure and Properties of Sintered Tungsten Carbides
Novotná, Hana ; Klakurková, Lenka (referee) ; Čelko, Ladislav (advisor)
This bachelor thesis deals with the structure and properties of sintered tungsten carbides. The literature review section concerns the development of sintered carbides, their composi-tion and structure, different types of carbides, the steps of the production of sintered car-bides, sintering technology and alternative materials for cutting tools. The experimental section deals with composition of WC-Co and is ascertained by the dependency coercivity on WC grain size and also on cobalt content. This work describes the measurement of WC grain size and measurement of the coercivity, one of the fundamental properties of sintered carbides.
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Technology of Galvanic Anodization of Non-ferrous Materials and Its Alloys
Remešová, Michaela ; Hadraba,, Hynek (referee) ; Čelko, Ladislav (advisor)
The thesis is focused on the theoretical description of the technology of anodizing of aluminium, magnesium, zinc and their alloys. In this work, methods for formation of oxide layers and the used chemical processes are described in detail. The experimental part of this work deals with formation of oxide layers on aluminium, magnesium and zinc of high purity under different conditions. Oxide layers of different thicknesses were created on all three experimental materials. Aluminium was anodized in a bath of 10% H2SO4, magnesium in the bath of 1 mol/dm3 NaOH, and zinc in the bath of 0.5 mol/dm3 NaOH. Processes were carried out at laboratory temperature. On the aluminium, continuous oxide layer was formed. Furthermore rule "312" was verified, that can indicatively be used for calculating the thickness of the resulting oxide layer on the aluminium. When using lower current of 0.08 and 0.2 A for magnesium anodizing, dark colored layer was created comparing to higher current of 0.5 A. More rough appearance of the oxide layer was produced with increasing voltage. Further, it was observed for magnesium that the resulting layer comprises of two sublayers. For zinc, black colored layer was created when the voltage 20 V and current from 0.4 to 0.5 A were used. In the layer, two sublayers were also observed. For lower voltage and current (0.05 A, 0.17 V), formation of the oxide layer on the zinc does not occur, but the crystallographic etching was observed.
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Mechanical alloying and compactization of metallic composite powders
Husák, Roman ; Čelko, Ladislav (referee) ; Hadraba, Hynek (advisor)
Master´s thesis is focus on the proces of mechanical alloying. It is the proces of modifying a hetegeneous mixture of powder materials into a homogeneous composite powder. Experiments are focus on three types of composite materials. A magnetic soft alloy Permalloy, ODS steel based on commercially available powder steel 434 LHC and low-activation high-chrome ODS steel 14Cr-2W. On composite powders are made a series of mechanical tests and chemicel analysis. Based on this tests and analysis it was possible to confirm the milling time needed to create fully homogeneous composite powder. Next step is compaction of composite powder into compact volume and another mechanical tests ana analysis of microstructure. In these analyzes to determine whether i tis necessary to use protective atmosphere during mechanical alloying. All three type of materials succesfull prepared by mechanical alloying. It was found that for created of a fully homogeneous composite powder is necessary to perform mechanical alloying for 24 hours. When processing of corrosion resistant materials, i tis possible to perform mechanical alloying in an air atmosphere. During mechanical alloying materials which are subject to oxidation, i tis necessary to use protective atmosphere.
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Formation of Hypereutectic Aluminium Alloys Using Sacrificial Coatings
Gregor, Martin ; Jech, David (referee) ; Čelko, Ladislav (advisor)
Master‘s thesis deals with the forming of hypereutectic aluminium alloys using sacrificial coatings. Literature research is focused on analysing the characteristics of aluminium and its alloys. Attention is also focused to the heat treatment of aluminium alloys and the influence of alloying elements on these alloys. Analysis of characteristics and increase the useful properties of Al - Ni alloys is another object of literary research. Attention is also focused to the analysis of thermal spraying methods by focusing on the principle of individual methods and the characteristics of the coatings made by these methods. The object of experimental part is to prepare the hypereutectic aluminium alloys using sacrificial nickel based coatings. This is an unconventional manufacturing process comprising coating the surface of the aluminium substrate with using HVOF technology and subsequent thermal exposure. Furthermore, the work deals with the metallographic evaluation of prepared samples with a particular focus on the influence of temperature and time of heat treatment on the final structure of the experimental samples.
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Formation of Diffusion Barriers Using Chemical Vapour Deposition Process
Foltýnek, Jaroslav ; Němec, Karel (referee) ; Čelko, Ladislav (advisor)
Masters thesis deals with formation of diffusion barrier coatings by means of powder mixtures chemical vapor deposition. Its theoretical part is focused on the problems with diffusion barriers formation, where predominantly three most commonly used methods are introduced, i.e. CVD from powder mixtures, active gasses and slurries. The experimental part of master thesis deals with the formation of nickel-aluminide diffusion barriers on Inconel 713LC superalloy substrate, where was for aluminization used six different powder mixtures at the temperature of 800 °C and dwell of 0, 2 and 5 hours.
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Low cycle fatigue of nickel superalloy IN713LC with TBC layer at high temperatures
Machala, Jan ; Čelko, Ladislav (referee) ; Juliš, Martin (advisor)
This thesis deals with the low cycle fatigue nickel-based superalloy IN713LC with applied TBC barrier at high temperature. The theoretical part is divided into four sections. The first one focuses on description of fatigue damage. The second one provides the basic characteristics of nickel-based superalloys. The third section describes the use of the surface layers - diffusion layers and thermal barriers and the fourth section deals with the influence of these layers on fatigue properties. Experimental part is focused on the evaluation of low cycle fatigue tests and on the explanation of the mechanisms of initiation and propagation of fatigue cracks. For the experimental part, fatigue samples were prepared by vacuum precision investment casting. TBC barrier was applied by atmospheric plasma spraying and consists of two sublayers - the lower metallic bond coating type CoNiCrAlY and top ceramic coating type YSZ. Low cycle fatigue tests were conducted under strain control at controlled temperature of 900 ° C. Fractographical analysis of fracture surfaces was carried out by using light and electron microscopy. Effect of applied barrier to fatigue life was determined - the parameters of Manson-Coffin and Basquin curve. A cyclic stress-strain curve was also obtained. The curves softening / hardening and number of transit cycles were determined. The obtained parameters and values from fatigue tests were compared with available data from fatigue tests of superalloy IN713LC without the layer, as applied AlSi type diffusion layer, at high temperatures. The initiation site on the fracture surfaces was determined within the fractographic evaluation and the influence of the layer on the initiation and propagation of fatigue cracks was discussed. A helpful tool was the assessment of longitudinal sections using scanning electron microscopy.
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Classification of microstructure of nickel-base superalloys with image analysis using
Volf, Milan ; Čelko, Ladislav (referee) ; Němec, Karel (advisor)
During operational conditions of internal combustion turbines of turbojet engines, the impeller are stressed by load cycles which vary in time, temperature and stress. In the course of operation, the blades are exposed to a considerable number of degradation effects, particularly high-temperature corrosion, fatigue processes and creep. The presented work is aimed at the study of the structure cast nickel-base superalloy INCONEL 713 LC, creep tests exposured. The structural changes (degradation) was clasification by the help of image analyses. Operational conditions of heat parts, used in gas turbines and turbo-compressors, were simulated by creep tests of Inconel 713 LC nickel superalloy during a constant load of temperatures ranging from 750 up to 950°C. Changes in the structure dependent upon time, temperature and stress applied were analysed by means of light and electron microscopy methods and image analyses after the fracture of test bars.
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High-temperature embrittlement of 14%Cr ODS ferritic steel in liquid lead environment
Dohnalová, Eva ; Čelko, Ladislav (referee) ; Hadraba, Hynek (advisor)
The thesis deals with the high-temperature embrittlement of 14%Cr ODS ferritic steel in liquid lead environment. The 14%Cr ferritic ODS steel ODM401 manufactured by powder metallurgy technology was used as an experimental material. The effect of the long-term annealing, surface corrosion attack in the melt Pb and Pb-Bi on the microstructure and mechanical properties was described. The subsequent microstructural changes were evaluated by means of scanning electron microscopy and transmission electron microscopy The mechanical behaviour of the experimental material was proven by means of microhardness test, impact test and static tensile test. The fractographical evaluation of fracture surfaces were performed on all samples. The surface attack and outstanding microstructural ganges were found after the long-time exposition of the steel in Pb/Pb-Bi melts at temperature 550°C/1000h and 500°C/1000h respectively. The embrittlement of the steel after exposition in Pb/Pb-Bi melts was comparable to the embrittlement after high-temperature annealing of the steel at temperature 650°C/1000h.
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