Original title:
Ion Transfer Voltammetry across the Polarized Ionic Liquid/Water Interface: Base for Electrochemical Sensors
Authors:
Langmaier, Jan ; Samec, Zdeněk Document type: Papers Conference/Event: Moderní Elektrochemické Metody /40./, Jetřichovice (CZ), 20211108
Year:
2021
Language:
eng Abstract:
Some electrochemical techniques such as voltammetry at the polarized interfaces between two\nimmiscible electrolyte solutions (ITIES) represent interesting alternatives to classical\nelectrochemistry. The benefit of the ion transfer voltammetry lies in the possibility of detection\nof ionic species which are not otherwise redox active. The methodology enables apart of direct\ndetermination of ionic samples (including pharmaceutical and clinical ones) also to monitor\nreaction processes (acido-basic, enzymatic, etc.), determination of reaction substrates and\nproducts in one experimental step, evaluation of reaction and transport kinetics, and estimation\nof lipophilicity of involved species.
Keywords:
electrochemical detection; ion transfer voltammetry; ionic liquid Project no.: GA20-07350S (CEP) Funding provider: GA ČR Host item entry: Sborník přednášek mezinárodní odborné konference XL. Moderní Elektrochemické Metody, ISBN 978-80-905221-8-3
Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR
(web)
Document availability information: Fulltext is available on demand via the digital repository of the Academy of Sciences. Original record: http://hdl.handle.net/11104/0325180