Original title:
Photochemical Derivatization of Helicenes.
Authors:
Jakubec, Martin ; Ghosh, I. ; Storch, Jan ; König, B. Document type: Papers Conference/Event: Advances in Organic, Bioorganic and Pharmaceutical Chemistry LIBLICE 2018 /53./, Lázně Bělohrad (CZ), 20181102
Year:
2018
Language:
eng Abstract:
This work is focused on the use of simple helicene derivatives as substrates for modern photochemical methods. Halogen containing substrates are transformed in the reductive pathway to helicenyl radicals, before being trapped by different radical traps. In the oxidative pathway, activated alkoxyhelicenes undergo photoredox catalyzed reactions, yielding various carbon-carbon, as well as carbon-heteroatom containing compounds.\n
Keywords:
helicene; photochemistry; substrates Project no.: FV10082 Funding provider: GA MPO Host item entry: Book of Abstracts, ISBN N
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.