Original title: New approaches to synthesis of C-deoxyribosides starting from C-alkynyldeoxyribosides
Translated title: Nový přístup k syntéze C-deoxyribosidů vycházející z C-alkynyldeoxyribosidů
Authors: Novák, P. ; Hocek, Michal ; Kotora, Martin
Document type: Papers
Conference/Event: Symposium on Chemistry of Nucleic Acid Components /14./, Český Krumlov (CZ), 2008-06-08 / 2008-06-13
Year: 2008
Language: eng
Abstract: [eng] [cze]
Various C-aryldeoxyribosides were conveniently prepared from the C-alkynyldeoxyribosides in good yields. The underlying strategy is based on [2+2+2]-cyclotrimerization catalyzed by rhodium and ruthenium complexes. The reaction could be carried out under ambient conditions or microwave irradiation depending on the degree of substitution. Různé C-aryldeoxyribosidy byly připraveny z C-alkynyldeoxyribosidů v dobrých výtěžcích. Popsaná strategie je postavena na [2+2+2]-cyklotrimerizacích katalyzovaných komplexy rhodia a ruthenia probíhajících za pokojové teploty nebo v mikrovlném reaktoru.
Keywords: C-deoxyribosides; cyclotrimerization; metal complexes
Project no.: CEZ:AV0Z40550506 (CEP), 1M0508 (CEP)
Funding provider: GA MŠk
Host item entry: Chemistry of Nucleic Acid Components, ISBN 978-80-86241-29-6

Institution: Institute of Organic Chemistry and Biochemistry AS ČR (web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences.
Original record: http://hdl.handle.net/11104/0161917

Permalink: http://www.nusl.cz/ntk/nusl-38949


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Research > Institutes ASCR > Institute of Organic Chemistry and Biochemistry
Conference materials > Papers