Original title: Ethylene Oxychlorination over CuCl2/γ-Al2O3 Catalyst in Micro- and Milli-structured Reactors.
Authors: Vajglová, Zuzana ; Moro, A. ; Kumar, N. ; Eränen, K. ; Peurla, M. ; Peltonen, J. ; Murzin, D.Yu. ; Salmi, T.
Document type: Papers
Conference/Event: International Congress of Chemical and Process Engineering CHISA 2018 /23./, Prague (CZ), 20180825
Year: 2018
Language: eng
Abstract: In the microreactor, the 1,2-dichlorethane selectivities of 4.7% and 53.6% were achieved with the ethene conversions of 1.6% and 6.4%, respectively. The other important product was chloroethane. The formation of vinyl chloride by-product of 1.6% was observed only at the highest temperature 250 °C with highest ethene conversion achieved (6.4%). No other by-products were observed. In the millireactor, the 1,2-dichlorethane selectivities exceeding 96% were achieved at ethene conversions higher than 11% within the entire experimental range. Chloroethane, vinyl chloride, 1,2-dichloroethylene (trans) were formed, but only in minor amounts.
Keywords: catalysts; ethylene oxychlorination; reactors
Host item entry: Program, ISBN N
Note: Související webová stránka: http://hdl.handle.net/11104/0287358
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.

Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0287358

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