Original title: Application of Cyclopentenediones for Preparation of Permselective Layers.
Authors: Vacek, J. ; Hrbáč, J. ; Matějka, P. ; Storch, Jan
Document type: Papers
Conference/Event: Moderní Elektrochemické Metody /34./, Jetřichovice (CZ), 20140519
Year: 2014
Language: eng
Abstract: In this contribution, we report that electrooxidation of PCD, phenolic cyclopentenedione, 2,2'-bis[4,5-bis(4-hydroxybenzyl)-2-(4-hydroxyphenyl)-cyclopent-4-ene-1,3-dione] results in the formation of stable films with permselective properties on metal and carbon surfaces. The electropolymerization process proceeds in neutral and alkaline aqueous medium at potentials higher than +0.6 V (vs. Ag/AgCl/3M KCl). The PCD polymer prepared was characterized by electrochemical methods, quartz crystal microbalance and optical spectroscopy techniques. The PCD film can be used for electrode coating and preparation of an anti-interference barrier. Thus, we performed SAR study which could open the door to developing novel functional films and electrochemical tools for bioactive compounds sensing.\n
Keywords: bioactives sensing; cyclopent-4-ene-1,3-dione; structure-activity relationship
Host item entry: Sborník přednášek, ISBN 978-80-905221-2-1
Note: Související webová stránka: http://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=1&SID=D4wO6yThxFfJG44uUuB&page=1&doc=1
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.

Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: http://hdl.handle.net/11104/0278561

Permalink: http://www.nusl.cz/ntk/nusl-370671


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