Studium nových silně korelovaných elektronových sloučenin REnTIn3n+2

Bartha, Attila

We have studied two different systems; RE2CoIn8 (RE = Pr, Nd, Dy) and CenTIn3n+2 (T = Pd, Pt; n = 2, 3). All compounds were prepared for the first time in the single crystalline form using the self-flux method. X-ray diffraction confirmed the tetragonal Ho2CoGa8 structure type for the RE2CoIn8 compounds and for the new phase Ce2TIn8. The novel phase Ce3PtIn11 adopts the structure of the Ce3PdIn11 compound, which represents a new structure type. Magnetic measurements revealed low anisotropy and the c-axis as the easy axis for all RE2CoIn8 compounds. Pr2CoIn8 is a paramagnet, while Nd2CoIn8 and Dy2CoIn8 order antiferromagnetically. Magnetization and specific heat measurements of Dy2CoIn8 revealed complex magnetic field-temperature phase diagram with various types of magnetic ordering. Specific heat measurements on multiphase Ce-Pd-In system revealed superconducting transition at Tc = 0.69 K arising from Ce2PdIn8 and another magnetic transition from Ce3PdIn11 at ~ 1.7 K. Ce3PdIn11 and Ce3PtIn11 compounds reveal two, probably magnetic transitions at T1 = 1.6 K, T2 = 1.45 K and T1 = 2.1 K and T2 = 2.0 K, respectively. Specific heat data qualifies both materials as heavy fermion compounds with γ = 290 mJ.mol-1 Ce K-2 and γ = 300 mJ.mol-1 Ce K-2 respectively.

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