Original title:
Frustrated Lewis pairs-assisted reduction of carbonyl compounds
Authors:
Marek, Aleš ; Pedersen, M. H. F. Document type: Papers Conference/Event: International Conference on Chemical Technology (ICCT) /4./, Mikulov (CZ), 20160425
Year:
2016
Language:
eng Abstract:
An alternative and robust method for the reduction of carbonyl groups by frustrated Lewis pairs (FLPs) is reported in this paper. With its very mild reaction conditions, good to excellent yields, absolute regioselectivity and the non-metallic character of the reagent, it provides an excellent tool for 1H, 2H as well as 3H chemistry. It is a new strategy for the one-pot synthesis of aromatic alcohols selectively labeled with heavy isotopes of hydrogen.
Keywords:
alcohol synthesis; carbonyl compounds; frustrated Lewis parts Host item entry: Proceedings of the 4th International Conference on Chemical Technology, ISBN 978-80-86238-94-4, ISSN 2336-811X
Institution: Institute of Organic Chemistry and Biochemistry AS ČR
(web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences. Original record: http://hdl.handle.net/11104/0268449