Original title:
Ruthenium (II) Complexes with 6,7-Diaza[5]phenacene.
Authors:
Beránek, Tomáš ; Žádný, Jaroslav ; Jakubík, Pavel ; Církva, Vladimír ; Storch, Jan Document type: Papers Conference/Event: Advances in Organic, Bioorganic and Pharmaceutical Chemistry Liblice 2016 /51./, Lázně Bělohrad (CZ), 20161111
Year:
2016
Language:
eng Abstract:
In this work we focused on preparation of novel bidentate and fully aromatic N,N-ligand and its ruthenium complexes. 6,7-Diaza[5]phenacene (1) was synthetized from 4-bromoisoquinoline by microwave-assisted tandem Hyama-Heck cross coupling reaction3 followed by photocyclization (Scheme 1). With 6,7-diaza[5]phenacene (1) in our hand, we prepared some new ruthenium(II) complexes (e.g. 2) , characterized them from structural point of view and determined some of their electronic and optical properties with regard to their application potential.
Keywords:
electronic proprties; photocatalysis; ruthenium cpmplexes Project no.: TA01010646 (CEP) Funding provider: GA TA ČR Host item entry: Book of Abstracts, ISBN N
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.