Original title: Utilization of electrochemically induced cleavage of various sulfonimides
Authors: Salvadori, Karolína
Document type: Papers
Conference/Event: Bažant postraguate conference 2023, Prague (CZ), 20230531
Year: 2023
Language: eng
Abstract: In this work, we describe the unexpected electrochemical cleavage of sulfonimides, providing a direct pathway to corresponding sulfonamides. For this purpose, 16 substances were synthesized and tested, reflecting the influence of different electron effects of -SO2Ph-R substituents, and the impact of the number of nosyl units present in molecules. In the case of octakis-nosylated calixarenes, the electrochemical cleavage via direct potential-controlled electrolysis was compared with conventional organic synthetic procedures. After electrolysis, all prepared sulfonamides were isolated in excellent yields.
Keywords: electrochemisty; green chemistry procedures; sulfonimides
Host item entry: Proceedings of Abstracts, ISBN 978-80-86186-29-0
Rights: This work is protected under the Copyright Act No. 121/2000 Coll.

Institution: Institute of Chemical Process Fundamentals AS ČR (web)
Original record: https://hdl.handle.net/11104/0343244

Permalink: http://www.nusl.cz/ntk/nusl-526203


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Research > Institutes ASCR > Institute of Chemical Process Fundamentals
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