Original title:
Application of capillary electrophoresis in forensic science: Analysis of fireworks
Authors:
Eliáš, Milan ; Maier, V. ; Knob, R. Document type: Papers Conference/Event: International Symposium Advances in Chromatography and Electrophoresis and Chiranal, Olomouc (CZ), 2012-06-11 / 2012-06-14
Year:
2012
Language:
eng Abstract:
In all samples of fireworks, K+, Na+, Ca2+ and Mg2+ ions were proved and quantified by the method of capillary zone electrophoresis using water solution of 10 mM 4-aminopyridine, titrated with hydroxyisobutyric acid to the pH 4.3, as background electrolyte and indirect UV-absorption detection at 200 nm. Pb2+ or Ba2+ ions were proved in few samples. The other selected inorganic cations were not proved in any sample of selected fireworks. NH4+ ions were not detected in any pre-blast samples, but they were established in some post-blast (glazed tiles) samples.
Keywords:
capillary zone electrophoresis; fireworks; metal cations Host item entry: Acta Universitatis Palackianae Olomucensis. Facultas Rerum Naturalium. Chemica 50S, ISBN 978-80-244-3115-4, ISSN 0232-0061
Institution: Institute of Organic Chemistry and Biochemistry AS ČR
(web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences. Original record: http://hdl.handle.net/11104/0216654