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Arsenic speciation in mining wastes - case studies in systems dominated by ferric sulfoarsenates
Jelenová, Helena ; Drahota, Petr (advisor) ; Filippi, Michal (referee) ; Jurkovič, Ľubomír (referee)
The aim of the thesis is to study behavior and mineralogy of arsenic in mine wastes with high levels of FeIII and SVI . Three methodological studies are related to (i) identification and characterization of secondary arsenic phases using a Raman spectrometry, (ii) chemical fractionation of arsenic in mine waste materials as observed by optimized sequential extraction, (ii) and investigation of thermodynamic properties of zýkaite. The mineralogy and mobility of arsenic was studied in mine waste material of five dumps located at three sites (Kaňk near Kutná Hora, Jedová jáma near Vejprty, and Dlouhá Ves) and in stalactite samples from two abandoned underground mines (Plavno and Mikulov near Teplice). Mineralogical and geochemical characterization of samples included standard methods and techniques. Chemical composition of solid and liquid (pore water, leachates) samples was performed using a XRF, ICP OES, ICP MS, etc. X-ray diffraction, Raman spectrometry and electron microscope equipped with microanalysis were the most frequent techniques used for mineralogical characterization of the solids. The results showed that the speciation of arsenic in the solid phase significantly varied among the studied sites and was a function of total concentration as well as proportion of the major components of...
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Treatment of mine waters rich in arsenic
Řáhová, Jaroslava ; Drahota, Petr (advisor) ; Kindlová, Helena (referee)
Summary: This bachalor thesis deals with treatment of mine waters rich in arsenic. First part is an overview of decontamination methods used for elimination of arsenic from water. Emphasised parts are focused on arsenic adsorption on Fe-oxides and hydroxides, particles which may be formed in mine waters; as well as on ODAS treatment system, widely used for mine waters decontamination. The experimental part is a study of decontamination process at mine treatment plant waters in Kaňk, Kutná hora. Extremely high concentrations of arsenic (77,72 mg/L) are found in acid mine drainage from closed Turkaňk mine. Results of this thesis signifies incorporation of arsenic and other elements dissolved in mine water into secondary forming Fe-oxyhydroxides within decontamination process.
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Treatment of mine waters rich in arsenic
Řáhová, Jaroslava ; Drahota, Petr (advisor) ; Kindlová, Helena (referee)
Summary: This bachalor thesis deals with treatment of mine waters rich in arsenic. First part is an overview of decontamination methods used for elimination of arsenic from water. Emphasised parts are focused on arsenic adsorption on Fe-oxides and hydroxides, particles which may be formed in mine waters; as well as on ODAS treatment system, widely used for mine waters decontamination. The experimental part is a study of decontamination process at mine treatment plant waters in Kaňk, Kutná hora. Extremely high concentrations of arsenic (77,72 mg/L) are found in acid mine drainage from closed Turkaňk mine. Results of this thesis signifies incorporation of arsenic and other elements dissolved in mine water into secondary forming Fe-oxyhydroxides within decontamination process.
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Hodnocení lokálního územního systému ekologické stability okolí Kutné Hory
Kupecká, Jana
My bachelor thesis deals with evaluation of the local teritorial system of ecological stability (hereinafter TSES) in Kutná Hora surroundings. As a base for field survey TSES framework from 1994 and map sources from the Land register were used. The main focus lied in determination of a current state of TSES. The elements were divided according to the type of TSES to bio-centres and bio-corridors. The results were processed into tables, maps and graphs. The work includes also description of changes in structural elements of TSES since 1994 until now. After the assessment of all the locations it can be concluded that the most of bio-centres and bio-corridors remained unchanged. Major changes lie in the change of the area of bio-centres.
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