|
|
Design of syngas cleaning by wet scrubber
Musilová, Petra ; Milčák, Pavel (referee) ; Baláš, Marek (advisor)
Gasification is a process which produces gas of low heating value, however, generated gas contains several pollutants. This thesis is dealing with the issue of purity and cleaning of generated gas. Theoretic part of thesis consists of research, describing the very process of gasification itself, mapping of possible pollutants appearing during gasification and particular ways of purifying gas, looking in detail at wet scrubbing with several scrubbing liquids. Further, it looks into proposition of conditions for wet scrubbing and balance of scrubbing liquids. Next part deals with calculation of purifying line. Main goal of calculations, is to determine the length of the pipeline, transfering polluted gas from the gasifier to the filter for elimination of solid particles and wet scrubber. Key aspect of length calculation was the input and output temperature of the gas, determined by characteristics of the filter. Calculation for wet scrubber istelf is also included, to detremine if the output temperature of the scrubbing liquid after the passage of the gas needs to be modified by additional cooling or heating. For experimental purposes, syngas generated by gasification of biomass, is gathered from the atmospheric gasifier Biofluid 2. Experiment itself inquires into the purity of the gas before and after the passage through solid particles filter and through the wet scrubber. The purpose of this thesis is to determine the chemical composition of gas before and after wet scrubbing, the difference of composition of tar gathered from purified and nonpurified gas and using gathered data to evaluate the effectiveness of wet scrubbing.
|
|
|
Syngas Cleaning in Hot Catalytic Filter
Lisý, Martin ; Skála, Zdeněk (advisor)
Disertation thesis deals with development of hot dolomite filter for the purposes of cleaning of gas polluted by biomass and waste gasification with ash and tar as well as sulphur and chlorine compounds as main pollutants. Gas is then cleaned so that it can be utilized in cogeneration units with combustion engines. This supports advancement of gasification techniques using decentralized power and heat generation especially for design of small scale units. Concrete aims of this thesis are stated in chapter 2. Experimental fluid gasification stend Biofluid 100 has been in operations at Brno University of Technology (BUT) since 2000 and it helps research of biomass and waste gasification. Development of the filter initially utilized needs and experience with the utility during cooperation of BUT and ATEKO Hradec Králové. Water scrubber was used for gas cleaning, however, this method proved to be ineffective. Alternative solutions were considered. Based on literature search, natural catalysts with limestone basis were opted. First part of the thesis presents literature search of this issue. Historic development and description of gasification process are briefly discussed as well as elementary classification of gasification generators. This part is followed by chapters dealing with gas pollutants. Tar – the most significant pollutant – is discussed in a separate chapter which presents tar formation, its classification, characteristics and methods for its removal. Brief summary of requirements on gas properties with respect to its utilization in various applications (especially in cogeneration units) follows. Other part of the literature search part focuses on methods of removal of tar from gas, especially on catalyst methods. Dolomite characteristics, description of dolomite calcination as well as simplified kinetic model of tar cracking using dolomite are presented. Based on literature search, laboratory and verification equipment was designed for the purposes of dolomite properties testing. Equipment description as well as description of experimental stend Biofluid 100 where the experimental tests were carried out can be found in introduction of the experimental part. This is followed by a complete description of pilot equipment design of hot dolomite filter with general description of experimental work process, brief characteristics of the fuel and catalytic material used. Final part of the work comprises of experiment results that were carried out on the pilot equipment. Focus is on efficiency of tar removal in connection with operation temperature, amount of catalytist and material used. Influence of these parameters on gas composition and energy intensity of the whole process under these conditions is mentioned as well. Possibility of autonomous unit operations without electricity heating is briefly outlined. Summary of the most significant results including the potential of future hot dolomite filter development is stated the final part of the thesis.
|
|
|
Waste gas combustion
Krček, Robin ; Lisá, Hana (referee) ; Baláš, Marek (advisor)
This bachelor thesis deals with the issue of using waste gases as fuel. The first part is focused on the production processes, properties and composition of selected waste gases. The following part is an overview of the methods used in the treatment and removal of pollutants from the gas. Finally, technologies that generate electrical, thermal or mechanical energy by burning waste gases are summarized.
|
|
|
Syngas composition influence on gas cleaning efficiency
Menšíková, Barbora ; Lisý, Martin (referee) ; Baláš, Marek (advisor)
The diploma thesis deals with the issue of pollution of the generated gas after the gasification process and its subsequent cleaning using a barrier filter. The theoretical part of thesis consists of research on the gasification process, the effects on the gasification process, pollutants in the gas and gas cleaning with a focus on the purification of gas from tar. The experimental part of this thesis is devoted to the gasification itself in a fluidized bed gasification reactor in order to test the effect of the catalyst, which was calcined dolomite, the composition of the gas at variable parameters of water vapor and the temperature inside the laboratory filter.
|
|
|
Removing of Gaseous Pollutants from the Air Masses on the Pilot-Plant Scrubber
Kalivoda, Josef ; Šulc,, Radek (referee) ; Moucha, Tomáš (referee) ; Svěrák, Tomáš (advisor)
The PHD thesis is focused on the absorption with chemical reaction on the pilot plant gas/liquid scrubber. The performance characterization of the apparatus is based on the absorption of carbon dioxide in to the 1\% sodium hydroxide sollution and includes pressure drops, liquid holdup, gas/liquid contact time and the capture effectiveness as well. The experimantal part of the thesis includes a complex of mathematical equations based on the Film theory. The complex of the mathematical equations allowed a calculation of the overall mass transfer coefficient for the type of the gas scrubber at the given experimental conditions.
|
|
|
Testing of the barrier filter charge for gas cleaning
Muzikářová, Věra ; Milčák, Pavel (referee) ; Baláš, Marek (advisor)
This diploma thesis deals with the issue of pollution of the generated gas during gasification. It consists of two parts. The first part is theoretical, where there is a search describing the course of gasification. There is also an overview of impurities in the generated gas and a description of methods suitable for gas purification. The second part of the work is focused experimentally, where various fillings of the barrier filter are tested during gas cleaning.
|
|
|
State of the art in the field of industrial waste gas cleaning
Kudela, Petr ; Jecha, David (referee) ; Brummer, Vladimír (advisor)
This bachelor thesis deals with the issue of cleaning of industrial waste gases. The legislation background of environmental protection, the role of BREF and current situation in the field of emission limits in the light of legislation of the Czech republic and the European union is described in the first part. Further the thesis displays short overview of the industrial waste gases cleaning technologies and the particular example of the evolution of emission limits is given. In the conclusion of the thesis there are the future planned changes of the BREFs shown and the gained knowledge is summarized.
|
|
|
The separation efficiency of air pollutants on pilot air scrubber
Magera, Lukáš ; Vlasák, Jaroslav (referee) ; Svěrák, Tomáš (advisor)
This diploma thesis deals with the separation process of air polutant on air scrubber. Absorption of carbon dioxide was carried out into 1 % solution of sodium hydroxide. Theoretical part is aimed at mass transportation, theory of absorption and examples of scrubbers. Experimental part focuses on some operating characteristics of scrubber and on optimisation of two-phase flow. The influence of hydrodynamic conditions on the absorption efficiency was found.
|
|
|
Waste Gasification
Sedláček, Tomáš ; Elbl, Patrik (referee) ; Lachman, Jakub (advisor)
The bachelor’s thesis deals with the topic of waste gasification. The first part includes the definition of waste with the focus on municipal solid waste, its evaluation as fuel on the basis of its contents and properties, in this case the heating value. Eventually the waste is compared with other normally used solid fuels. The second part presents and describes the thermal processes applied to waste-to-energy technologies, where the gasification is explained in more detail, its final products, the content of contaminants in these products and their removal. The next part deals with technologies used for waste gasification. The last part deals with the issue of waste gasification in the Czech republic.
|
|
|
Waste gas combustion
Krček, Robin ; Lisá, Hana (referee) ; Baláš, Marek (advisor)
This bachelor thesis deals with the issue of using waste gases as fuel. The first part is focused on the production processes, properties and composition of selected waste gases. The following part is an overview of the methods used in the treatment and removal of pollutants from the gas. Finally, technologies that generate electrical, thermal or mechanical energy by burning waste gases are summarized.
|
guest ::
