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Poly(methylene blue) modified carbon based electrodes for the determination of sulfhydryl-containing compounds
Zlámalová, Magda ; Janda, Pavel ; Nesměrák, K.
This research presents the study of electrochemical polymerization of phenothiazine derivative, methylene blue (MB). Electrochemical pro perties and analytical application of resulting electrocatalytically active poly(methylene blue) (pMB) have been investigated. Three various carbon-based substrates: basal plane of highly oriented pyro lytic graphite (HOPG), pencil graphite electrode (PGE) and carbon fibre micro electrode (CFE) have been used. Aforementioned electrodes modified with the polymer (HOPG/pMB, PGE/pMB and CFE/pMB) have been prepared by potential cycling in aqueous electrolyte solution containing dissolved monomeric methylene blue. Electrocatalytic activity of three developed electrode systems towards hydrogen sulphide has been compared. Developed electrodes have been further investigated as potential sensors for sulfhydryl-containing compounds.
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Poly(Methylene Blue) Modified Carbon-based Electrodes for Electrochemical Detection of Hydrogen Sulfide
Zlámalová, Magda ; Janda, Pavel ; Nesměrák, K.
A comparative electrochemical study has been carried out of the electropolymerization of phenothiazine derivative, methylene blue (MB). Electrochemical properties of resulting electrocatalytically active methylene blue polymer (pMB) have been studied on three various carbon-based substrates: basal plane of highly oriented pyrolytic graphite (HOPG), pencil-graphite electrode (PGE) and carbon fibre micro electrode (CFE). Electrodes modified with the polymer (HOPG/pMB, PGE/pMB and CFE/pMB) have been prepared by potential cycling in aqueous electrolyte solution containing dissolved monomeric methylene blue. Electrocatalytic activity of three developed electrode systems towards hydrogen sulphide has been compared. Developed electrodes have been further investigated as potential sensors for sulfhydryl-containing compounds.
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Electrochemical Characterization of Poly(methylene Blue) Modified Graphite Electrodes
Zlámalová, Magda ; Janda, Pavel ; Nesměrák, K.
This work deals with electrochemical study of methylene blue (MB) polymerization as well as characterization of deposited conductive film on basal plane highly oriented pyrolytic graphite (HOPG) and pencil-graphite electrode (PGE). Poly(methylene blue) modified electrodes (HOPG/pMB and PGE/pMB) have been prepared by potential cycling in aqueous electrolyte solution containing methylene blue monomer. It has been found that electrochemical properties and electrocatalytic activity of deposited film are greatly influenced by the type of electrode substrate. Developed electrodes have been further investigated as potential sensors for sulfhydryl-containing compounds.
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New electrochemical cell for studies of phthalocyanines
Hudská, V. ; Janda, Pavel ; Nesměrák, K.
We have developed a new type of electrochemical cell for electrochemical studies of phthalocyanines. The cell employs a HOPG as a working electrode covered by a thin layer of dichlorobenzene with dissolved phthalocyanine. The layer of dichlorobenzene solution is overlaid by aqueous supporting electrolyte solution where the reference and counter microelectrodes are immersed.
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