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Conducting polymers and their use in supercapacitors
Gottwald, Tomáš ; Zatloukal, Miroslav (referee) ; Dvořák, Petr (advisor)
This work deals with the issues of using conducting polymers for supercapacitor electrodes and optimizing the technological process for their production. The work focuses on optimizing the amount of polymer used in order to achieve the most capacity. The methodology consists of creating an appropriate experimental electrode and subsequent measuring its associated capacity with BioLogic. This approach leads to creating charts which show the dependencies of capacity on the amount of polymer used.
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Properties of carbon materials for supercapacitors
Štorek, Ondřej ; Dvořák, Petr (referee) ; Sedlaříková, Marie (advisor)
The Master’s Thesis deals with supercapacitators based on principle of eletrical double layer. At the outset there is an explanation of supercapacitor working principal. We discussed advantages and disavantages supercapacitators compared with other related elements in electrotechnics. Materials based on carbon and their structure for production supercapacitators are described too. In next part of Thesis we mention different methods and techniques for the measurement and the evaluation of supercapacitators‘s capacities. Optimal materials for production supercapacitators are presented in conclusion.
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Liquid electrolytes for supercapacitors
Bill, Jan ; Dvořák, Petr (referee) ; Sedlaříková, Marie (advisor)
This work deals with the preparation of liquid electrolytes from different types of aprotic solvents with the aim of their application as electrolytes in electrochemical supercapacitors. Different sorts of aprotic solvents have been chosen, in which the following forms of salts were used: LiBF4, LiClO4,LiPF6. In the next part of the work, the properties of these solvents were measured and the best electrolyte, according to the biggest possible capacity of the system, was chosen. In the theoretical part of this work, the physical principle of supercapacitors and their propeties are described. It deals with electrolytes, their division and with the properties that are appropriate for supercapacitors. The experimental part of the work describes the process of preparation of the samples of electrodes, electrolytes and the techniques of measuring their capacities.
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Diagnostics of plasma chemical deposition processes using organometallic precursors
Sahánková, Hana ; Dvořák, Pavel (referee) ; Krčma, František (advisor)
The aim of this work is diagnostic of plasma chemical deposition thin films based on organometallic precursors. Thin layers have recently become one of the most used methods for surface treatment of materials. They are used as a protective, functional layer, they improve surface properties of materials or increase or reduce the adhesion to various compounds. Plasma polymers are a modern trend in surface treatment technology. Their structure is different from classical polymers. The titanium (IV)isopropoxide was chosen as a monomer example, which is frequently used as a monomer for photocatalytic TiO2 films plasma deposition. These thin films are very promising for the removal of various air and water pollutants and thus they can significantly help in the increase of the environmental quality. Measurements took place on a commercial device Plasmatreater AS 400. The theoretical part describes the background needed for the study and diagnostics of plasma processes and technologies. The optical emission spectroscopy was chosen as a diagnostic method, and thus its principles are outlined in the theoretical part. Infrared spectroscopy and X-ray photoelectron spectroscopy were applied for the diagnostics of prepared thin films and they are also described in the theoretical part. The experimental part contains two sections. The first section is dedicated to the plasma diagnostics by optical emission spectroscopy. Discharge was generated in nitrogen or in the air. Measurements were performed at seven different duty cycles and at two different flow rates for each of the working gases. The molecular bands of nitrogen first negative and second systems, CN violet bands, and atomic lines of oxygen and nozzle elements (Cu, Cr) were identified in the spectra. The titanium lines, and bands of TiO were determined if the precursor was added. Electron temperature was calculated using chromium lines, and electron temperature maps were obtained for continuous mode and pulse mode with duty cycle 70% for nitrogen plasma with 500 sccm precursor flow. Similar discharge maps were also processed using the selected line of titanium (520 nm) TiO band (625 nm) again for the same discharge conditions. Furthermore, the dependences of the same quantities were obtained along the discharge axis as a function of duty cycle in both gases with precursor flow of 1000 sccm. The second part of results brings material analyzes of the deposited samples. The peaks of anatase and rutile have been identified by infrared spectroscopy. Using X-ray photoelectron spectroscopy, we found that our layers contain a significant amount of non-dissociated precursor. Moreover, a large number of radicals, which can interact with atmospheric gases, was determined on the surface. These radicals are removable by annealing or by ion etching. All results obtained during this research can significantly help us to improve the quality of deposited layers and allow us also some prediction of the thin film properties at given plasma conditions. Of course, further experimental as well as theoretical studies should be completed to obtain complete knowledge needed for the wide applications of these layers.
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Place of Sustainable Development
Dvořák, Pavel ; Rudiš, Viktor (referee) ; Koleček, Ivan (advisor)
Ostrava city as lost it's relationships to the medieval history of the city centre. There are not any historical places, spaces or palaces, with free public spaces like the old castles and palaces in the cities. In the place of the former German House, destroyed after the the World war II is a rest of public space, which could be a part of the city sustainability concept. The project let's the rest of the historcial garden there like a countryard between two houses of the new Sustainable Development Centre. The sustaiable concept is to let there be a free space in the highly dense block structure of the modern city.
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The lifting platform for europalletes
Dvořák, Pavel ; Kašpárek, Jaroslav (referee) ; Pokorný, Přemysl (advisor)
This bachelor thesis solves a design of the lifting platform for euro-pallets. The main content of the thesis is the design dimensions of the lifting table, design and calculation of the lift drive and stress calculations of some loaded parts of the structure. The thesis includes an appendix with assembly drawing of the lifting platform and assembly drawing of the table frame.
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Overview of sensors suitable for active flow control methods
Kopylov, Gleb ; Dvořák, Petr (referee) ; Brožek, Petr (advisor)
The main purpose of this bachelor thesis was to create the overview of the sensors developed for the future active flow control applications and overview the sensors already used in the active flow control applications. The sensors have to fulfil several requirements, so selection for the overview was based on the real flight test programs results, which were described in the first part of the thesis. The sensors technology description and operation principles were included in the second part of the thesis.
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The deposition of thin films by the ion sputtering IBS/IBAD
Hudeček, Jan ; Pavera, Michal (referee) ; Dvořák, Petr (advisor)
The submitted bachelor’s thesis are dealed with concept and design of holder of new palette, which is determine for deposition equipment, which belongs to institue of physical engineering and which is called as Kaufmann. Introductory chapters of bachelor’s thesis deals about possibilities of production of thin films, ways of growth of thin films and introduction to vakuum physics. Next chapter is given to current deposition and current deposition equipment Kaufmann. In the next chapter are descriptions of construct solution of holder of new palette and construct solution of palette. The last chapter is given to calibration and optimalization of deposition with new palette.
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Deposition of Indium Tin Oxide and study of its optical properties
Olivíková, Gabriela ; Kvapil, Michal (referee) ; Dvořák, Petr (advisor)
This work is focused on preparation and deposition of thin layers of indium tin oxide (ITO) by ion beam sputtering (IBS) and ion beam assisted deposition (IBAD). In the theoretical part, the electrical and optical properties, preparation methods, and applications are reviewed. In the experimental part, the optical and transport properties of deposited films are investigated by spectroscopic methods. It is shown that simultaneous bombardment of the surface with oxygen ions with energy 80 eV results in increase of transmittance in the visible range of spectrum. IBAD thus confirmed as a suitable method for modification of optical properties.
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Optical properties of infrared plasmonic antennas fabricated by FIB technique
Biolek, Vladimír ; Dvořák, Petr (referee) ; Kvapil, Michal (advisor)
The bachelor thesis deals with plasmonic nanostructures for mid-infrared region of electromagnetic spectrum. In the first part, there are discussed theoretical description of electromagnetic field and description of properties of plasmonic nanostructures. Then the manufacturing methods of the plasmonic nanostructures for mid-infrared region of electromagnetic spectrum are discussed using focused ion beam, and measurement of these nanostructures are discussed using Fourier transform-infrared spectroscopy.
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