|
|
Polymer composites with controlled interphase
Zvonek, Milan ; Knob, Antonín (referee) ; Čech, Vladimír (advisor)
Cieľom diplomovej práce je príprava polymerných kompozitov vyztužených sklenenými vláknami s riadenou medzifázou za použitia metódy plazmochemickej depozície z plynnej fáze a monomeru tetravinylsilanu. Teoretická časť je zameraná na literárnu rešerš o plazme, plazmovej polymerácií, tenkých vrstvách a kompozitoch. Experimentálna časť popisuje použité materiály a aparaturu použitú na povrchovú modifikáciu sklenených vlákien a prípravu vláknom vyztužených kompozitov. Povrchová úprava sklenených vlákien prebiehala za rôznych depozičných podmienok. Chemické a mechanické analýzy vytvorenej medzivrstvy prebiehali za použitia FTIR spektrometrie a vrypového testu. Vliv povrchovej úpravy bol zistený pomocou získanej interlaminárnej šmykovej sily použítím testu krátkych trámečkov.
|
|
|
Surface modification of glass fibers using plasma nanotechnology
Sedlák, Filip ; Knob, Antonín (referee) ; Čech, Vladimír (advisor)
Diploma thesis is aimed at deposition of thin films on glass fibers using plasma-enhanced chemical vapor deposition from tetravinylsilane as a monomer. Such surface modified glass fibers were used as reinforcements for fabrication of polymer composites with unsaturated polyester resin as a matrix. Chemical and optical properties of prepared thin films were characterized using infared spectroscopy and spectroscopic ellipsometry. An influence of deposited thin films on the shear strength of composite material was observed using short-beam shear test.
|
|
|
NUMERICAL ESTIMATION OF MICRO-CRACK PATHS IN POLYMER PARTICULATE COMPOSITE
Majer, Z. ; Náhlík, Luboš
Determination of composite mechanical behavior is one of important part during the composite tailoring. The aim of the present work was to estimate a micro-crack behavior in a polymer particulate composite. The composite was investigated by means of the finite element method -using ANSYS software. A two-dimensional three-phase finite element model was developed to analyze the crack growth behavior. The assumptions of the linear elastic fracture mechanics were considered and the Maximum Tangential Stress (MTS) criterion was used to predict the direction of the crack propagation. The effect of the elastic modulus of the interphase on the micro-crack propagation was investigated. The properties of matrix and particles were taken from experiment. It was shown that the interphase properties influence the stress intensity factor KI as well as the micro-crack paths. The results of this paper can contribute to a better understanding of the micro-crack propagation in particulate composites with respect to the interphase.
|
|
|
Surface modification of glass fibers for polymer composites
Knob, Antonín ; Marek,, Aleš (referee) ; Burša, Jiří (referee) ; Čech, Vladimír (advisor)
The doctoral thesis is aimed at preparation of glass fiber reinforced polymer composites with controlled interphase formed by plasma-polymerized tetravinylsilane and tetravinylsilane/oxygen thin films. The thin polymer films of specific physico-chemical properties and thickness were deposited to improve interfacial adhesion of glass fiber/polyester composites. The fiber surface modification was performed by using plasma enhanced chemical vapor deposition in low-temperature RF plasma operating in an various effective power range and different treatment time. Test results were examined in relation to the interlayer thickness and different treatment conditions. The prepared interlayers were analyzed to evaluate physico-chemical composition and properties (XPS, RBS, ERDA, FTIR and spectroscopic elipsometry). Selected mechanical properties were evaluated by AFM. Mechanical response of plasma interlayers was evaluated by short beam shear test and direct method of testing the interfacial shear strength using microindentation. The interphase shear failure was controlled by the shear strength at the interlayer/fiber interface as follows from experimental and model data.
|
|
|
Mechanical activation of chemical reactions at interfaces of MDF composites
Matoušek, David ; Másilko, Jiří (referee) ; Šoukal, František (advisor)
The thesis deals with study of mechnochemical activation of chemical reactions at interphase of MDF composites. MDF composites are high-perspective composite materials on polymer-cement base. They excel especially in terms of flexural strengths. High flexural stregth is caused by binding interactions between the polymer and the cement. This interactions arise due to mechanochemical activation of raw material mixture at the stage of production. This work focuses on the creation of artificial cement-polymer interphase by contacting the surfaces of two molded tablets (polyvinyl alcohol and monocalcium aluminate), activation of chemical reactions at interphase by means of specially designed appartus, which achieves good plane-parallelism of activation surfaces and good definability of activation conditions (shear rate, pressure). After experiments under different conditions, the activated surfaces are analyzed by SEM, EDS, XPS and FT-IR.
|
|
|
Některé aspekty chování polymerních částicových kompozitů
Hutař, Pavel ; Knésl, Zdeněk ; Majer, Zdeněk ; Prod’homme, G. ; Náhlík, Luboš ; Nezbedová, E. ; Veselý, P.
Computation of the internal stress and strain fields in the microstructural level of the studied composite and understanding of microcracks behaviour in the interaction with particles is the first step to understanding the global behaviour of the composite based on microstructural morphology. Therefore, particle reinforced composite has been modelled as a three-phase material with homogenously distributed coated particles and numerically studied on the microscopic scale using finite element modelling. The FEM modelling and unit cell models provide an effective tools for parametric study of the three-phase composite mechanical properties.
|
|
|
Efekt velikosti částic na lomové chování polypropylenového kompozitu
Nezbedová, E. ; Knésl, Zdeněk ; Hutař, Pavel ; Majer, Zdeněk ; Veselý, P.
The addition of mineral fillers to polypropylene (PP) can profoundly change the mechanical properties of polymer system. The properties of the particles themselves (size, shape, and material properties) can have significant effect on the global behaviour of composite, particularly on its toughness and stiffness. This contribution is focused on effects of particles size and their density on fracture toughness of polyprophylen particulate composite. The effect was studied from the experimental as well as from the theoretical point of view. The change of fracture toughness was estimated with utilisation of linear elastic fracture mechanics approach. The composite was modelled as a three-phase material with homogeneously distributed coated particles and numerically simulated using the finite element program ANSYS.
|
|
|
Influence of particles shape on fracture toughness of PP-based particulate composite
Majer, Zdeněk ; Knésl, Zdeněk ; Hutař, Pavel
Polymeric particulate composites with thermoplastics are of great practical importance due to the possibility of modifying mechanical properties and reducing the price/volume ratio of resulting material. The properties of the particles themselves (size, shape, material properties) can have a significant effect on the global behaviour of the composite. Generally, the addition of rigid particles to a polymer matrix will have an embrittling effect on the composite. The presence of the particles significantly influences the cure reaction resulting in the formation of a third phase known as the interphase, which possesses a property distinct from those of the matrix and the particles. The particle-reinforced composite (PP-CaCO3) was modeled as a three-phase material with homogeneously distributed coated particles. The main aim of the article is estimate an effect of the interphase properties on microcrack behaviour.
|
guest ::
