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Changes in chemical composition of surface water at the model catchment Lesni potok during the spring snowmelt 2009
Navrátil, Tomáš ; Dobešová, Irena ; Rohovec, Jan ; Buchtová, Jana
Changes of surface water chemistry during the spring snowmelt were evaluated at the forested experimental catchment Lesni Potok found in National Reservation Area Voděradské bučiny. The pH value of surface waters decreased and together with high discharge it launched changes of solutes concentrations. As a good indicator of groundwater in the discharge were evaluated concentrations of Si and isotopic signature of 18O-H2O. The concentration of the main anion SO42- in waters of Lesni potok oscillated during the spring snowmelt in dependence of ratio between melting snow, soil solution, precipitation and groundwater. During the period of increased penetration of surface soil horizons with the water from melting snow causing the increase of DOC concentrations. Concentrations of DOC determined the export of total Fe. Concentrations of Al with DOC did not correlate because the driving factor on concentrations of Al at Lesni Potok is the surface water pH. Concentrations of NO3- were rapidly decreasing during the snowmelt and at the end of this episodic event NO3- concentrations were trivial due to the rapid flushing of soil horizons.
Atmospheric deposition in the vicinity of the limestone-quarry Čertovy schody
Špičková, Jitka ; Dobešová, Irena ; Vach, Marek ; Burian, Miloš ; Skřivan, Petr
Atmospheric precipitation samples were collected in the Bohemian Karst, (30 km SW from Prague, Czech Republic) at six localities in the vicinity of the limestone-quarry Čertovy schody during years 1996-2003. Samples were analyzed for major components (Na+, K+, Mg2+, Ca2+, F-, Cl-, NO3-, HCO3-, SO42-) and trace metals (Cu, Mn, Fe, Zn, Pb, Be, As, Sr, Cd, Al, Cr). Deposition fluxes were calculated from more than 10 000 elemental analyses of samples collected monthly. The fluxes of monitored substances show temporal and spatial variability. The most marked attribute is the strong affection by local emission sources confirmed by the investigation of seasonal variability, temporal trend and correlation analysis.

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