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Blended alkali-activated aluminosilicate binders
Mizerová, Cecílie ; Bayer, Patrik (referee) ; Rovnaník, Pavel (advisor)
The first part of the work presents a summary of the current knowledge of two-component blended alkali-activated binders based on blast furnace slag, fly ash, metakaolin and ground brick with emphasis on their workability, microstructure, mechanical properties and durability. In the experimental part the alkali-activated binders with different ratio of fly ash and metakaolin were made to compare their workability and mechanical properties. The binder structure was evaluated by means of scanning electron microscopy (SEM) and mercury intrusion porosimetry. From the literature review and my own achievements it can be concluded that the combination of single precursors has a positive effect on the majority of the assessed properties of the material.
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Fibre coposites with alkali -activated slag matrix
Pluskalová, Barbora ; Bayer, Patrik (referee) ; Rovnaník, Pavel (advisor)
This master thesis is concerns the preparation of Alkali Activated Materials, specifically Alkali Activated Slag (AAS), with the addition of fiber reinforcement. Alkali Activated Materials have great potential for use in construction practice. However, their use is limited by certain undesirable properties, which can be diminished by adding fiber reinforcement. This thesis deals with the influence of carbon fibers (2 % by weight of the binder) and carbon nanotubes (0,2 % by weigh of the binder) on the mechanical properties, microstructure and shrinkage of AAS. The results of the experiments which were carried out correspond with the literary research. Conclusions of this thesis agree with research published in original scientific papers.
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Rehydration of alkali-activated slag after high temperature loading
Fialová, Barbora ; Bayer, Patrik (referee) ; Rovnaník, Pavel (advisor)
Ground granulated blast furnace slag is a by-product of the steel industry and is often used in combination with ordinary Portland cement as a binder in concrete. When concrete is exposed to high temperatures, physical and chemical transformations lead to significant loss of mechanical properties. This study aims to investigate the effect of high temperatures and rehydration on the mechanical properties, microstructure and phase composition of alkali activated slag. The results of the research could make an important contribution to decisions made concerning the reconstruction of structures affected by fire. In suitable cases it would be possible to regenerate parts of a structure instead of totally rebuilding it.
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Binary alkali-activated composite materials with brick powder
Mizerová, Cecílie ; Bayer, Patrik (referee) ; Rovnaník, Pavel (advisor)
The thesis is focused on the application of brick powder in production of binary alkali-activated binders with metakaolin, slag and fly ash. The theoretical part summarizes recent fields of use of the ceramic waste in construction and binder industry and prerequisite properties of the brick powder for alkaline activation. Brick powder based geopolymers made in the experimental work were tested for their mechanical properties, porosity and microstructure, flow properties of the fresh geopolymers were evaluated by rheometric measurements. In accordance with the results it can be concluded that brick powder could be a suitable precursor for blended binders with metakaolin and slag, these samples exhibited good mechanical properties and microstructure characteristics. The combination with fly ash was less applicable due to a rapid setting, hardening retarder used in these binders caused significant deterioration of the mechanical properties of the material.
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Methods of Indetification of Historic Mortars
Kurfürstová, Nela ; Bayer, Patrik (referee) ; Rovnaníková, Pavla (advisor)
The thesis is describing short survey on metods to help identify individual components that was used in the history for the production of mortar. The work is focused especially for plaster whose main binder is lime. The lime was in the past used to mortatrs to improve the properties for example adhesion to the substráte, workability, hygrophobic and more. The aim of practical part was to analyze the obtained historical mortar according to the methods mentioned in the theoretical part – determining individual components contained in historical mortar, composition ratio and proposal for the composition of the repair mortars. These knowledge can to help for reconstrution of historical objects.
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Effect of Grain Size of Waste Glass on Properties of Alkali Activated Aluminosilicate Composites
Novák, Václav ; Vyšvařil, Martin (referee) ; Bayer, Patrik (advisor)
The diploma thesis is focused on the use of the waste glass with different fineness on alkali - activated composites, mainly based on slag and fly ash. The theoretical part is focused on materials that are most used for alkaline activation - slag, fly ash and their composites with waste glass. The theoretical part also deals with the alkaline activation of composites from these materials and the factors that influences the microstructure and properties of these composites. In the experimental part were prepared composites from slag and fly ash with a waste glass as substitute. These composites then have been examined on mechanical properties and microstructure, also how different fineness of glass influences these properties. Then it will be decided whether it is economically advantageous grinding waste glass to finer fractions
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Binary alkali-activated composite materials with brick powder
Mizerová, Cecílie ; Bayer, Patrik (referee) ; Rovnaník, Pavel (advisor)
The thesis is focused on the application of brick powder in production of binary alkali-activated binders with metakaolin, slag and fly ash. The theoretical part summarizes recent fields of use of the ceramic waste in construction and binder industry and prerequisite properties of the brick powder for alkaline activation. Brick powder based geopolymers made in the experimental work were tested for their mechanical properties, porosity and microstructure, flow properties of the fresh geopolymers were evaluated by rheometric measurements. In accordance with the results it can be concluded that brick powder could be a suitable precursor for blended binders with metakaolin and slag, these samples exhibited good mechanical properties and microstructure characteristics. The combination with fly ash was less applicable due to a rapid setting, hardening retarder used in these binders caused significant deterioration of the mechanical properties of the material.
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Effect of cellulose ethers on mechanical properties of lime mortar
Skoupil, Jakub ; Bayer, Patrik (referee) ; Vyšvařil, Martin (advisor)
The subject of the thesis is to conduct an extensive literature review on the topic of effect of cellulose ethers on the mechanical properties of lime mortars. The theoretical part is devoted to the composition and production of cellulose ethers, which are available on the industrial market. On the basis of the review, the design of lime mortars using different kind of cellulose ethers has been conducted and after curing the tests of mechanical properties of mortars were performed and evaluated.
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Influence of waste glass in the alkali activated aluminosilicate
Novák, Václav ; Rovnaník, Pavel (referee) ; Bayer, Patrik (advisor)
Theoretical part of this work will be examine the most common materials from which geopolymers are produced and their alkaline activation and properties. In addition, the work will be examine glass itself and alkaline activation of glass. This paper also will be investigate possibilities of making geopolymers from glass or geopolymers with the addition of glass. In the experimental part geopolymers will be made and their basic material will be replaced with part of the glass. The mechanical properties and microstructure of these mixed geopolymers will be examined and how the glass influence the properties of these geopolymers.
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Immobilization of heavy metals in the cement matrix with the admixture of natural zeolite
Semerádová, Nikol ; Bayer, Patrik (referee) ; Vyšvařil, Martin (advisor)
Heavy metals released to the natural ecosystem constitute significant risks not only for organisms, but also for water supplies in the nature. There are a number of analytical methods for the determination of heavy metals. Each of them is suitable for different element and its character. Since the results of the analysis are applied during the solidification and stabilization, it is necessary to ensure the highest correlation between hazardous waste and solidification medium for maximum inhibition of toxic ions. This work investigates the stabilization of heavy metals binders based on cement base with admixture of the natural zeolite and its possible use for the solidification of heavy metals in soluble form.
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