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Testing of a transparent model of a pressure-swirl nozzle
Sapík, Marcel ; Pech, Ondřej (referee) ; Jedelský, Jan (advisor)
The aim of the thesis is to put a transparent scaled PMMA model of the pressure swirl nozzle into operation, which includes, the selection of working fluids and the preparation of a test set to allow measurements using optical methods (LDA, PDA, PIV, high-speed visualization). The theoretical part describes the basic theory of atomization, optical measurement methods and deals with the problems of optical transition in optically complex systems. It also includes an extensive search for transparent liquids and materials of enlarged models that have been used in experiments, which often aim to match light refractive indices between these materials. In the practical part, attention is paid to the preparation of the test set and tests of chemical effects of several selected liquids on PMMA material are conducted, including a summary of experience with their use, as there was a permanent damage to the material. Several LDA measurements followed, using kerosene, p-cymene, 1-bromonaphthalene and water, evaluated the effect of the refractive index difference on the results. It turned out that no observable influence occurred if the refractive index difference between the nozzle material and the liquid was small. In addition, a visualization of internal flow through a high-speed camera was made. The practical part closes the static pressure measurement in the nozzle chamber, where the pressure ratio was measured on the walls of the chamber as well as on its axis. The measurement confirmed that the pressure on the chamber walls is constant and varies with the distance from the chamber axis.
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The influence of atomizing media on the quality of the combustion of liquid fuels
Bojanovský, Jiří ; Skryja, Pavel (referee) ; Bělohradský, Petr (advisor)
The aim of the present work was to experimentally investigate the influence of atomizing medium on combustion properties of methyl-ester of rapeseed oil. The experiments were carried out in a water-cooled horizontal combustion chamber. The pneumatic atomization using effervescent atomizer was used in test. As atomizing medium compressed air and superheated steam was chosen. The tests were performed at GLR = 15, 20 and 25 %. The experiments were focused on the investigation of the flame characteristics, quality of combustion, emissions, temperature of flue gas, distribution of heat fluxes and stability of combustion. Results revealed that atomization by compressed air is more efficient (approximately by 6 %), on the other hand it leads to higher NO emissions (for 15 mg/mN3 due to higher in-flame temperature).
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HG-AAS with atomization in a dielectric barrier plasma discharge: method optimization and analytical applications
Zurynková, Pavla ; Kratzer, Jan (advisor) ; Kanický, Viktor (referee)
The aim of this diploma thesis was to optimize in detail atomization conditions for antimony hydride in a novel plasma atomizer based on a dielectric barrier discharge (DBD) with atomic absorption spetrometric detection. Argon was found as the best DBD discharge gas employing a flow rate of 50 ml min-1 Ar while the DBD power was optimized at 30 W. Analytical figures of merit including interference study of As, Se and Bi have been subsequently investigated and the results compared to those found in an externally heated quartz tube atomizer (QTA). The limit of detection reached in DBD (0.15 ng ml-1 Sb) is comparable to that observed in QTA (0.14 ng ml-1 Sb). Finally, possibility of stibane preconcentration in a DBD atomizer was studied. Preconcentration efficiency of 102 ± 6 % was found under optimized conditions.
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A novel AAS atomizer based on a dielectric barrier plasma discharge
Novák, Petr ; Kratzer, Jan (advisor) ; Kanický, Viktor (referee)
Atomization of arsine in a novel hydride atomizer for atomic absorption spectrometry (HG-AAS) was thoroughly optimized. This plasma atomizer is based on a dielectric barrier discharge (DBD). Sensitivity and detection limit reached 0.48 s ng-1 As and 0.16 ng ml-1 As, respectively, under optimum atomization conditions (Ar discharge using a flow rate of 60 ml min-1 Ar, DBD power 17 W). Analytical figures of merit reached in DBD are comparable to those found in an externally heated quartz tube multiatomizer (MMQTA) that was chosen as a model of conventional approach to hydride atomization in HG-AAS. An extent of interferences (Se, Sb, Bi) during As determination was investigated comparing both MMQTA and DBD atomizers. The later one was found to be more resistant towards interferences. A simple preconcentration of As in a DBD atomizer was reached after oxygen introduction into the Ar plasma in the DBD resulting in analyte retention in the atomizer followed by its volatilization once the oxygen flow is switched off. Preconcentration efficiency of 100 % was reached and detection limit improvement by a factor of ten was achieved (0.01 ng ml-1 As, preconcentration period 300 s).
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Sensitivity increasing of gold determination by electrochemical volatile species generation with AAS detection
Vacek, Tomáš ; Hraníček, Jakub (advisor) ; Rychlovský, Petr (referee)
This thesis is focused on increasing the senstitivity of gold determination by electrochemical volatile species generation using two different types of electrolytic cells in continuous flow setting. Externally heated quartz tube atomizer was used as means of atomization and detection of gold with atomic absorption spectrometer. Generation parameters were optimized for electrolytic cell with an ion exchange (nafion) membrane. After selection of new cathode material (Cu) the carrier gas (Ar) flow rate was optimized, where an additional inlet of carrier gas was found to have possitive effect on increasing the sensitivity of determination of gold and efficiency of volatile specie transport to the atomizer. Experiments with Antifoam B showed possitive effect on generation, thus calibration was carried out for optimized experimetal conditions reaching detection limit of 0,53 mg.dm−3 . The efficiency of volatile specie transfer from liquid to gaseous phase was determined between 60 - 65 % by measuring the residual gold content in liquid waste by F-AAS method. Subsequently the effieciency of electrolytic generation of volatile gold specie with radioactive tracer isotopes and autoradigraphy was determined to 0,6 %. These methods confirmed adsorption of generated species on apparatus surface. Using ICP-MS as...
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The influence of atomizing media on the quality of the combustion of liquid fuels
Bojanovský, Jiří ; Skryja, Pavel (referee) ; Bělohradský, Petr (advisor)
The aim of the present work was to experimentally investigate the influence of atomizing medium on combustion properties of methyl-ester of rapeseed oil. The experiments were carried out in a water-cooled horizontal combustion chamber. The pneumatic atomization using effervescent atomizer was used in test. As atomizing medium compressed air and superheated steam was chosen. The tests were performed at GLR = 15, 20 and 25 %. The experiments were focused on the investigation of the flame characteristics, quality of combustion, emissions, temperature of flue gas, distribution of heat fluxes and stability of combustion. Results revealed that atomization by compressed air is more efficient (approximately by 6 %), on the other hand it leads to higher NO emissions (for 13 mg/mN3 due to higher in-flame temperature).
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Plasma spraying from liquids: plasma liquid interaction and coating build up
Tesař, Tomáš ; Mušálek, Radek ; Medřický, Jan ; Lukáč, František
Plasma spraying from liquid feedstocks is a rapidly developing field of thermal spraying since the coatings prepared from liquids exhibit some unique features, such as high hardness, thermal shock resistance or low thermal and electric conductivity. The key factor influencing the final coating character and properties is the input material which may be in the form of a suspension or a solution. Parameters of the selected suspension (solids concentration, viscosity, surface tension, chemical composition, etc.) or solution (concentration, etc.) determine its interaction with the plasma jet which strongly influences the coating buildup. This proceeding introduces the problematics of the interaction between the liquid feedstock material with the plasma jet and presents the way of evaluation of the coating buildup.
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Vizualization of liquid break-up from atomization nozzles
Janáčková, Lada ; Bělka, Miloslav (referee) ; Jedelský, Jan (advisor)
V oblasti mechaniky tekutin hraje vizualizace významnou roli. Fotografie poskytují vhled do zásad chování tekutin a obecně pomáhají k lepšímu pochopení fyzikálních procesů proudění. Tato práce se zabývá vizualizací rozpadu kapalin u rozprašovacích trysek. Práce popisuje základy rozpadu kapalin, stejně jako metody pro vizualizaci. Dále je v práci probrána a experimentálně testována analýza prvků ve vizualizačních metodách. Laboratorní testy byly provedeny na malé tlakové vířivé trysce určené pro spalování kerosinu v proudovém leteckém motoru a část experimentů byla provedena na tlakové spirálové trysce. Práce dokumentuje vliv zdroje světla na kvalitu fotografie. Chování spreje je navíc analyzováno pomocí makrofotografie se zaměřením na primární rozpad, který hraje hlavní roli v celém procesu tvorby spreje a sprejových charakteristik.
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Design and construction of transparent nozzle for visualization and measurement of the internal flow
Sapík, Marcel ; Fojtlín, Miloš (referee) ; Jedelský, Jan (advisor)
This thesis deals with design and construction of transparent nozzle for research of internal flow of liquids. The objective was to design potential construction of the nozzle and make a manufacturing drawing. The theoretical part deals with basics of atomization including properties of liquids and describes basic optical methods for internal flow in a nozzle. In the research part of this thesis, a number of construction solutions has been picked to serve as an inspiration for the final shape of the nozzle. Its construction is elaborated in the last part along with a description of the process, a manufacturing drawing, and a visual documentation with a 3D model.
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Influence of operational conditions on spray characteristics of twin-fluid atomizers
Zaremba, Matouš ; Lízal, František (referee) ; Jedelský, Jan (advisor)
This master’s thesis deals with measurement of spray characteristics of Effervescent atomizers intended for burning waste and heavy fuels. Atomizers were tested on cold test bench by means of Phase Doppler Anemometry. Spray characteristics were evaluated for many different regimes of pressure, temperature and Gas to liquid ratio. The aim of this measurement is to compare flow regimes and their influence on the quality of spray characteristics. The theoretical part describes basic fundamental principles of liquid atomization, effervescent atomization and principles of laser diagnostic methods. The practical part is engaged with improvements in test bench and setting up and optimization of the laser measuring system. Results contain visualization of spray, velocity profiles and drop size distribution in various operating flow regimes of the jet.
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