Original title: Electrochemical Characterization of Self-Assembled Monolayers of Ru(Terpyridine) 2(2+) Transition Metal Complexes
Authors: Kocábová, Jana ; Nováková Lachmanová, Štěpánka ; Valášek, M. ; Hromadová, Magdaléna
Document type: Papers
Conference/Event: Modern Electrochemical Methods /44./, Jetřichovice (CZ), 20250519
Year: 2025
Language: eng
Abstract: Electrochemical properties of new transition metal complexes based on Ru(terpyridine)22+ with different sizes of tripodal anchors on gold bead electrode surfaces were studied by cyclic\nvoltammetry and electrochemical impedance spectroscopy. The presence of specialized functional groups in a tripodal arrangement enabled a successful Au-S bond formation and reproducible\npreparation of a well-defined compact self-assembled monolayer. Calculations of the surface concentration and the area per adsorbed molecule were done. The electron transfer rate constants of\nRu-tripods were determined and compared.
Keywords: cyclic voltammetry; transition metal complexes; tripodal anchor
Project no.: EH22_008/0004558
Funding provider: GA MŠk
Host item entry: Proceedings of the International Conference 44th Modern Electrochemical Methods, ISBN 978-80-908947-2-3

Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR (web)
Document availability information: Fulltext is available on demand via the digital repository of the Academy of Sciences.
Original record: https://hdl.handle.net/11104/0366915

Permalink: http://www.nusl.cz/ntk/nusl-679995


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Research > Institutes ASCR > J. Heyrovsky Institute of Physical Chemistry
Conference materials > Papers