Original title: A polarizable reference electrode
Authors: Mareček, Vladimír
Document type: Papers
Conference/Event: Moderní elektrochemické metody /42./, Jetřichovice (CZ), 20230522
Year: 2023
Language: eng
Abstract: New concept of a reference electrode for electrochemical systems resolves a problem of a poor \npotential stability of refence electrodes based on the distribution of a strongly \nhydrophobic common cation between two immiscible electrolyte solutions (TTTES). The use of a \npolarizable metal electrode instead of a classical reference electrode is demonstrated in \n a modified conventional four-electrode cell with TTTES. A simple battery operated potentiostat \ncontrols the working electrode potential in a three-electrode configuration. The working metal \nelectrode then serves as a polarizable reference organic solvent electrode in a four-electrode \nsystem for the polarization of the water/organic solvent interface.\n\n
Keywords: chloride extraction; liquid/liquid interface; reference electrode
Project no.: GA22-32631S (CEP)
Funding provider: GA ČR
Host item entry: Moderní elektrochemické metody /42./. Sborník přednášek, ISBN 978-80-908947-0-9

Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR (web)
Document availability information: Fulltext is available on demand via the digital repository of the Academy of Sciences.
Original record: https://hdl.handle.net/11104/0343388

Permalink: http://www.nusl.cz/ntk/nusl-526223


The record appears in these collections:
Research > Institutes ASCR > J. Heyrovsky Institute of Physical Chemistry
Conference materials > Papers