Original title:
Acid/base properties and reactivity of square planar complexes
Authors:
DVOŘÁČKOVÁ, Olga Document type: Doctoral theses
Year:
2022
Language:
cze Abstract:
Complexes of platinum and other transition metals are important compounds with many applications including anticancer treatment. This thesis is based on the computational studies dealing with the properties and reactivity of square planar complexes. We showed that the central metal atom acts as a Lewis acid in standard coordination bonds but is able to interact as a Lewis base when being in contact with a Lewis acid. Substitution(s) of the nonleaving ligand(s) enabled a fine-tuning of the reactivity of Pt(II) compounds.
Keywords:
Lewis acid; Lewis base; platinum; reactivity; substitution effect; trans effect Citation: DVOŘÁČKOVÁ, Olga. Acid/base properties and reactivity of square planar complexes. N. Hrady, 2022. disertační práce (Ph.D.). JIHOČESKÁ UNIVERZITA V ČESKÝCH BUDĚJOVICÍCH. Přírodovědecká fakulta
Institution: University of South Bohemia in České Budějovice
(web)
Document availability information: Fulltext is available in the Digital Repository of University of South Bohemia. Original record: http://www.jcu.cz/vskp/67476