Original title:
Spectroelectrochemistry of 1,10-phenantrolines Substituted by Pyrrolidine and Phenothiazine Redox-active Units
Authors:
Sokolová, Romana ; Wantulok, J. ; Fiedler, Jan ; Nycz, J. ; Degano, I. Document type: Papers Conference/Event: Moderní elektrochemické metody /41./, Jetřichovice (CZ), 20220522
Year:
2022
Language:
eng Abstract:
Compounds based on 1,10-phenanthroline (Phen) and their complexes are used in many fields, such as a stabilizing agent in the synthesis of nanoparticles, catalysts in homogeneous catalysis and as a semiconductor in organic light-emitting diodes (OLED) due to their coordination abilities. In this work, 1,10-phenanthrolines functionalized by pyrrolidine and phenothiazine units were studied by electrochemical methods. Cyclic voltammetry resulted in several oxidation and reduction voltammetric peaks. Structure-activity relationship was investigated using in situ spectroeletrochemistry, spectrophotometry, infrared spectroscopy and chromatography.
Keywords:
1,10-phenanthroline; Electrochemistry; Oxidation mechanism; Reduction mechanism Host item entry: 41. Moderní elektrochemické metody. Sborník přednášek, ISBN 978-80-905221-9-0
Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR
(web)
Document availability information: Fulltext is available on demand via the digital repository of the Academy of Sciences. Original record: http://hdl.handle.net/11104/0331821