Original title: Electrochemical Characterization of Molecular Conductors Containing Redox Switching Element
Authors: Nováková Lachmanová, Štěpánka ; Vavrek, František ; Sebechlebská, Táňa ; Šebera, Jakub ; Kolivoška, Viliam ; Lukášek, J. ; Balzer, N. ; Valášek, M. ; Mayor, M. ; Hromadová, Magdaléna
Document type: Papers
Conference/Event: Moderní Elektrochemické Metody /40./, Jetřichovice (CZ), 20211108
Year: 2021
Language: eng
Abstract: Electrochemical properties of new molecules containing tripodal anchor and redox switching\nelement have been studied by cyclic voltammetry and DFT quantum mechanical calculations.\nComparison of their redox properties with individual organometallic [Ru(terpy)2]2+t3+ and\n[Os(terpy)2]2+t3+ redox centers shows that covalently bonded tripodal anchor does not\ncompromise the reversibility of a redox process and has no effect on the stability of new\nmolecules. New molecular conductors have smaller HOMO-LUMO gap and both are oxidized\nat only slightly more positive potentials after tripodal substitution making them suitable for the\ndevelopment of molecular conductors with switching abilities.
Keywords: Cyclic voltammetry; DFT calculations; Tripodal anchor
Project no.: GA21-13458S (CEP)
Funding provider: GA ČR
Host item entry: Sborník přednášek mezinárodní odborné konference XL. Moderní Elektrochemické Metody, ISBN 978-80-905221-8-3

Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR (web)
Document availability information: Fulltext is available on demand via the digital repository of the Academy of Sciences.
Original record: http://hdl.handle.net/11104/0325348

Permalink: http://www.nusl.cz/ntk/nusl-508280


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Research > Institutes ASCR > J. Heyrovsky Institute of Physical Chemistry
Conference materials > Papers