Original title: Electrochemistry of Phospholes
Authors: Koláčná, Lucie ; Liška, Alan ; Ludvík, Jiří
Document type: Papers
Conference/Event: Moderní Elektrochemické Metody /40./, Jetřichovice (CZ), 20211108
Year: 2021
Language: eng
Abstract: Seventeen pentasubstituted phospholes with expected application in organic electronics were\nsynthesized and characterized electrochemically and by UV-vis spectra. Quantum chemical\ncalculations ofredox potentials and HOMO-LUMO energies were performed and experimental\nand theoretical data were successfully correlated. Tuning of redox properties can be achieved\nby combination of induction and resonance effects of substituents, extension / diminution of\nthe pi- delocalized system and by steric changes which affect intramolecular electron\ncommunication.
Keywords: Electrochemistry; Pentasubstituted phospholes; UV-vis spectra
Project no.: GA18-12150S (CEP)
Funding provider: GA ČR
Host item entry: Sborník přednášek mezinárodní odborné konference XL. Moderní Elektrochemické Metody, ISBN 978-80-905221-8-3

Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR (web)
Document availability information: Fulltext is available on demand via the digital repository of the Academy of Sciences.
Original record: http://hdl.handle.net/11104/0325340

Permalink: http://www.nusl.cz/ntk/nusl-508276


The record appears in these collections:
Research > Institutes ASCR > J. Heyrovsky Institute of Physical Chemistry
Conference materials > Papers