Original title: Structural, Redox and Spectrometric Characterization of Energetic Material FOX-7 (2,2-dinitroethene-1,1-diamine) in Solution
Authors: Šimková, Ludmila ; Ludvík, Jiří
Document type: Papers
Conference/Event: Moderní elektrochemické metody /36./, Jetřichovice (CZ), 20160523
Year: 2016
Language: eng
Abstract: The investigation of energetic materials, especially organic nitro-amino-derivatives, always has attracted attention of physical chemists. However, published articles demonstrate lack of systematic study of molecules based on aliphatic backbones, rather than aromatic structures. This work represents the first systematic electrochemical and spectrometric characterization of 2,2-dinitroethene-1,1-diamine (FOX-7) in aqueous and aprotic solvent. Based on the results obtained from combination of electrochemistry with spectrometric methods, the actual structure of FOX-7 in various media was revealed, its reducibility described and radical intermediates as well as products were intercepted, isolated and characterized.
Keywords: 2,2-dinitroethene-1,1-diamine; FOX-7; structure
Project no.: GA13-21704S (CEP)
Funding provider: GA ČR
Host item entry: XXXVI. Moderní elektrochemické metody. Sborník přednášek, ISBN 978-80-905221-4-5

Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR (web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences.
Original record: http://hdl.handle.net/11104/0259944

Permalink: http://www.nusl.cz/ntk/nusl-251398


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Research > Institutes ASCR > J. Heyrovsky Institute of Physical Chemistry
Conference materials > Papers