Original title:
Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene
Translated title:
Chemie klastrových boranový analogů cyklopentadienidového aniontu a ferrocenu
Authors:
Štíbr, Bohumil Document type: Papers Conference/Event: European Meeting on Boron Chemistry/3./, Průhonice (CZ), 2004-09-12 / 2004-09-16
Year:
2004
Language:
eng Abstract:
[eng][cze] Isomeric tricarbollide and phosphacarbollide anions of general nido structures [7,8,9-E3B8H8](1-) and [7,8,10-E3B8H8](2-)are borane-cluster analogues of the cyclopentadienide anions as they are monoanionic and contain an open pentagonal face capable of donatig five electrons into the metal shell.Isomerní trikarbollidové a fosfadikarbollidové anionty typu (E3B8H8)(1-) (E ´= CH, P) jsou klastrovými analogy cyklopentadienidového aniontu a poskytují s přechodnými kovy komplexy podobné ferrocenu.
Keywords:
boranes; carboranes Project no.: CEZ:AV0Z4032918 (CEP), LN00A028 (CEP) Funding provider: GA MŠk Host item entry: EUROBORON 3
Institution: Institute of Inorganic Chemistry AS ČR
(web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences. Original record: http://hdl.handle.net/11104/0015302